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Cited by 215

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Solution-Based Straight and Branched CdSe Nanowires

Open access
Grebinski, James W., Hull, Katherine L., Zhang, Jing, Kosel, Thomas H., Kuno, Masaru·2004·Chemistry of Materials

Abstract

Confined straight and branched CdSe nanowires (NWs) are synthesized using a solution-based approach which leverages advances in the synthesis of colloidal CdSe quantum dots (QDs) with incipient approaches for the seeded (solution) synthesis of semiconductor NWs. The resulting straight and branched NWs have typical diameters below 10 nm with accompanying lengths between 1 and 10 μm. In the case of branched NWs, tripod, v-shaped, and y-shaped morphologies are observed. Variations in this preparation lead to higher order structures with multiple arms. The branching transition is discussed, and a possible mechanism based upon geminate NW nucleation is proposed. Such solution-grown straight, branched, and higher-order NWs exhibit potentially interesting optical, electrical, and transport properties due to their narrow radii below the corresponding bulk exciton Bohr radius of CdSe. Furthermore, this transition from straight to branched morphologies opens up avenues for investigating not only size- but also shape-dependent optical/electrical properties of one-dimensional (1D) and quasi-1D materials.

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Metadata

Authors
Grebinski, J. W., Hull, K. L., Zhang, J., Kosel, T. H., & Kuno, M.
Venue
Chemistry of Materials
Published
2004-11-17
Volume
16
Issue
25
Pages
5260-5272
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W4246467490
Cited by
215
References
1
FWCI
11.46
Type
journal article
Language
en
Open access
green

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