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A Simple Large-Scale Synthesis of Nearly Monodisperse Gold and Silver Nanoparticles with Adjustable Sizes and with Exchangeable Surfactants
Abstract
Oleylamine-ligated gold and silver nanoparticles can be conveniently synthesized by reaction of tetrachloroauric acid or silver acetate with oleylamine in refluxing toluene, hexane, or 1,2-dichlorobenzene. The sizes of the colloids can be controlled with the solvent, reaction temperature, and reaction time. The gold nanoparticles spontaneously organize into micrometer-size colloidal crystals. Reactions of the gold and silver nanoparticles with aliphatic and carboxylic acid-functionalized thiols affords the ligand-exchanged nanoparticles as colloids that, depending on the surfactants, can be soluble in aqueous or nonaqueous solvents.
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Citations
Cites
Theory, Production and Mechanism of Formation of Monodispersed Hydrosols
LaMer, V. K., & Dinegar, R. H. (1950) · Journal of the American Chemical Society · doi:10.1021/ja01167a001 · Cited by 3,894
Cited by
Mechanisms of Nucleation and Growth of Nanoparticles in Solution
Thanh, N. T. K., Maclean, N., & Mahiddine, S. (2014) · Chemical Reviews · doi:10.1021/cr400544s · Cited by 3,399
Negligible Particle-Specific Antibacterial Activity of Silver Nanoparticles
Xiu, Z.-M., Zhang, Q.-B., Puppala, H. L., Colvin, V. L., & Alvarez, P. J. J. (2012) · Nano Letters · doi:10.1021/nl301934w · Cited by 2,108
Applications of gold nanoparticles in cancer nanotechnology
Cai, W. (2008) · Nanotechnology, Science and Applications · doi:10.2147/nsa.s3788 · Cited by 851
Kinetics and Mechanisms of Aggregative Nanocrystal Growth
Wang, F., Richards, V. N., Shields, S. P., & Buhro, W. E. (2014) · Chemistry of Materials · doi:10.1021/cm402139r · Cited by 560
Silver Nanoparticles Capped by Oleylamine: Formation, Growth, and Self-Organization
Chen, M., Feng, Y.-G., Wang, X., Li, T.-C., Zhang, J.-Y., & Qian, D.-J. (2007) · Langmuir · doi:10.1021/la700553d · Cited by 422
Metadata
- Authors
- Hiramatsu, H., & Osterloh, F. E.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-05-28
- Volume
- 16
- Issue
- 13
- Pages
- 2509-2511
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2001372852
- Cited by
- 645
- References
- 1
- FWCI
- 12.82
- Type
- journal article
- Language
- en
- Open access
- closed
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