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Silver Nanoparticles Capped by Oleylamine: Formation, Growth, and Self-Organization
Abstract
Nearly monodisperse silver nanoparticles have been prepared in a simple oleylamine-liquid paraffin system. Intensive study has found that the formation process of silver nanoparticles could be divided into three stages: growth, incubation, and Ostwald ripening stages. Ultraviolet-visible spectroscopy, transmission electron microscopy (TEM), and high-resolution TEM have all demonstrated the occurrence of Ostwald ripening, which could result in better control over the size and size distribution of silver nanoparticles. SAXS (small-angle X-ray scattering) results show that the as-obtained silver nanoparticles can self-assemble into ordered arrays. The possible reduction mechanism of silver ions by oleylamine is related to the Ag+-mediated conversion of primary amines to nitriles.
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Citations
Cited by
Baruah, B., Gabriel, G. J., Akbashev, M. J., & Booher, M. E. (2013) · Langmuir · doi:10.1021/la305068p · Cited by 391
A Review of Silver Nanoparticles: Synthesis Methods, Properties and Applications
Natsuki, J. (2015) · International Journal of Materials Science and Applications · doi:10.11648/j.ijmsa.20150405.17 · Cited by 277
Insight into Electrochemical CO 2 Reduction on Surface-Molecule-Mediated Ag Nanoparticles
Kim, C., Eom, T., Jee, M. S., Jung, H., Kim, H., Min, B. K., & Hwang, Y. J. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b01862 · Cited by 265
Effects of stabilizers on the synthesis of Pt3Cox/C electrocatalysts for oxygen reduction
Kim, J. W., Heo, J. H., Hwang, S. J., Yoo, S. J., Jang, J. H., Ha, J. S., Jang, S., Lim, T.-H., Nam, S. W., & Kim, S.-K. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.06.137 · Cited by 25
Wang, S., Wu, Z., Wang, Y., Hong, H., Zhang, L., Chen, Z., Zhang, P., Chen, Z., Zhang, W., Zheng, S., et al. (2023) · Regenerative Biomaterials · doi:10.1093/rb/rbac082 · Cited by 22
Metadata
- Authors
- Chen, M., Feng, Y.-G., Wang, X., Li, T.-C., Zhang, J.-Y., & Qian, D.-J.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-04-11
- Volume
- 23
- Issue
- 10
- Pages
- 5296-5304
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W1976755207
- Cited by
- 422
- References
- 0
- FWCI
- 7.33
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, M., Feng, Y.-G., Wang, X., Li, T.-C., Zhang, J.-Y., & Qian, D.-J. (2007). Silver Nanoparticles Capped by Oleylamine: Formation, Growth, and Self-Organization. Langmuir. https://doi.org/10.1021/la700553d
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