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Crystalline Carbon Hollow Spheres, Crystalline Carbon−SnO2 Hollow Spheres, and Crystalline SnO2 Hollow Spheres: Synthesis and Performance in Reversible Li-Ion Storage
Abstract
A few types of crystalline hollow structures, crystalline carbon hollow spheres (750 nm), crystalline carbon hollow spheres with encapsulated or decorated 1−3 nm SnO 2 nanoparticles, and crystalline SnO 2 hollow spheres (200−300 nm) synthesized by various methods, have been evaluated for reversible Li + storage. The experimental results showed noticeable improvements in a number of performance areas such as specific capacity, rate capability, and cyclability. The improvements could be attributed to a high degree of crystallinity, which increases the electronic conductivity, and the facile transport of Li ions in a hollow shell with nanoscale thickness, which significantly shortens the solid-state diffusion length.
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Cites
Yoon, S. B., Chai, G. S., Kang, S. K., Yu, J.-S., Gierszal, K. P., & Jaroniec, M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0423466 · Cited by 271
Cited by
Synthesis, Properties, and Applications of Hollow Micro-/Nanostructures
Wang, X., Feng, J., Bai, Y., Zhang, Q., & Yin, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00731 · Cited by 1,456
Porous electrode materials for lithium-ion batteries–how to prepare them and what makes them special
Vu, A., Qian, Y., & Stein, A. (2012) · Advanced Energy Materials · doi:10.1002/aenm.201200320 · Cited by 719
Liu, L., Yang, X., Lv, C., Zhu, A., Zhu, X., Guo, S., Chen, C., & Yang, D. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b12427 · Cited by 192
Metadata
- Authors
- Wang, Y., Su, F., Lee, J. Y., & Zhao, X. S.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-02-10
- Volume
- 18
- Issue
- 5
- Pages
- 1347-1353
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2002855928
- Cited by
- 387
- References
- 1
- FWCI
- 28.34
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, Y., Su, F., Lee, J. Y., & Zhao, X. S. (2006). Crystalline Carbon Hollow Spheres, Crystalline Carbon−SnO2 Hollow Spheres, and Crystalline SnO2 Hollow Spheres: Synthesis and Performance in Reversible Li-Ion Storage. Chemistry of Materials. https://doi.org/10.1021/cm052219o
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