The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite
Abstract
A detailed analysis of the thermal expansion mechanism of graphite oxide to produce functionalized graphene sheets is provided. Exfoliation takes place when the decomposition rate of the epoxy and hydroxyl sites of graphite oxide exceeds the diffusion rate of the evolved gases, thus yielding pressures that exceed the van der Waals forces holding the graphene sheets together. A comparison of the Arrhenius dependence of the reaction rate against the calculated diffusion coefficient based on Knudsen diffusion suggests a critical temperature of 550 °C which must be exceeded for exfoliation to occur. As a result of their wrinkled nature, the functionalized and defective graphene sheets do not collapse back to graphite oxide but are highly agglomerated. After dispersion by ultrasonication in appropriate solvents, statistical analysis by atomic force microscopy shows that 80% of the observed flakes are single sheets.
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Citations
Cites
Electric Field Effect in Atomically Thin Carbon Films
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Adsorption of Gases in Multimolecular Layers
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Experimental observation of the quantum Hall effect and Berry's phase in graphene
Zhang, Y., Tan, Y.-W., Stormer, H. L., & Kim, P. (2005) · Nature · doi:10.1038/nature04235 · Cited by 13,435
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Two-dimensional atomic crystals
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Cited by
The chemistry of graphene oxide
Dreyer, D. R., Park, S., Bielawski, C. W., & Ruoff, R. S. (2010) · Chem. Soc. Rev. · doi:10.1039/b917103g · Cited by 11,653
Recent advances in graphene based polymer composites
Kuilla, T., Bhadra, S., Yao, D., Kim, N. H., Bose, S., & Lee, J. H. (2010) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2010.07.005 · Cited by 3,406
Graphene/Polymer Nanocomposites
Kim, H., Abdala, A. A., & Macosko, C. W. (2010) · Macromolecules · doi:10.1021/ma100572e · Cited by 3,406
Self-citationGraphene-based semiconductor photocatalysts
Xiang, Q., Yu, J., & Jaroniec, M. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15172j · Cited by 2,730
Efficient Reduction of Graphite Oxide by Sodium Borohydride and Its Effect on Electrical Conductance
Shin, H., Kim, K. K., Benayad, A., Yoon, S., Park, H. K., Jung, I., Jin, M. H., Jeong, H., Kim, J. M., Choi, J., et al. (2009) · Advanced Functional Materials · doi:10.1002/adfm.200900167 · Cited by 2,283
Metadata
- Authors
- McAllister, M. J., Li, J.-L., Adamson, D. H., Schniepp, H. C., Abdala, A. A., Liu, J., Herrera-Alonso, M., Milius, D. L., Car, R., Prud'homme, R. K., & Aksay, I. A.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-05-25
- Volume
- 19
- Issue
- 18
- Pages
- 4396-4404
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2065062234
- Cited by
- 3,569
- References
- 7
- FWCI
- 50.83
- Type
- journal article
- Language
- en
- Open access
- closed
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