The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Synthesis and Characterization of an Amino Functionalized MIL-101(Al): Separation and Catalytic Properties
Abstract
A new MIL-101 material based on aluminum and containing amine functional groups has been synthesized. The pure phase NH 2 -MIL-101(Al) can only be formed in very specific synthesis conditions, where both the metal source and the solvent used play a key role. The resulting porous solid shows a high thermal and chemical stability, decomposing at temperatures above 650 K in air. The NH 2 -MIL-101(Al) framework offers an excellent trade off for separation of CO 2: the combination of high stability, acceptable capacity at low adsorbate partial pressures, high selectivity, and fast regenerability makes this new material a very attractive candidate for applications like natural gas or biogas upgrading. CO 2 capacities up to 62 wt % are obtained at room temperature and 3 MPa. In addition to an excellent separation performance, the NH 2 -MIL-101(Al) shows a high activity in the basic catalyzed Knoevenagel condensation of benzaldehyde with ethyl cyanoacetate at 313 K even in an as apolar a solvent as toluene (turn over frequency, TOF = 1.8 h –1 ).
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Cites
An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO 2 and CH 4
Couck, S., Denayer, J. F. M., Baron, G. V., Rémy, T., Gascon, J., & Kapteijn, F. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900555r · Cited by 988
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Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Kökçam-Demir, Ü., Goldman, A., Esrafili, L., Gharib, M., Morsali, A., Weingart, O., & Janiak, C. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00609e · Cited by 895
Design and fabrication of mesoporous heterogeneous basic catalysts
Sun, L.-B., Liu, X.-Q., & Zhou, H.-C. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00090d · Cited by 386
Heterogeneous Catalysis for Tandem Reactions
Climent, M. J., Corma, A., Iborra, S., & Sabater, M. J. (2014) · ACS Catalysis · doi:10.1021/cs401052k · Cited by 361
Linker functionalized metal-organic frameworks
Ali Akbar Razavi, S., & Morsali, A. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213023 · Cited by 341
Metadata
- Authors
- Serra-Crespo, P., Ramos-Fernandez, E. V., Gascon, J., & Kapteijn, F.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-04-26
- Volume
- 23
- Issue
- 10
- Pages
- 2565-2572
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2320627461
- Cited by
- 538
- References
- 1
- FWCI
- 26.04
- Type
- journal article
- Language
- en
- Open access
- closed
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