The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.
Synthesis and Characterization of an Amino Functionalized MIL-101(Al): Separation and Catalytic Properties
Abstract
A new MIL-101 material based on aluminum and containing amine functional groups has been synthesized. The pure phase NH 2 -MIL-101(Al) can only be formed in very specific synthesis conditions, where both the metal source and the solvent used play a key role. The resulting porous solid shows a high thermal and chemical stability, decomposing at temperatures above 650 K in air. The NH 2 -MIL-101(Al) framework offers an excellent trade off for separation of CO 2: the combination of high stability, acceptable capacity at low adsorbate partial pressures, high selectivity, and fast regenerability makes this new material a very attractive candidate for applications like natural gas or biogas upgrading. CO 2 capacities up to 62 wt % are obtained at room temperature and 3 MPa. In addition to an excellent separation performance, the NH 2 -MIL-101(Al) shows a high activity in the basic catalyzed Knoevenagel condensation of benzaldehyde with ethyl cyanoacetate at 313 K even in an as apolar a solvent as toluene (turn over frequency, TOF = 1.8 h –1 ).
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Cites
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Cited by
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Metadata
- Authors
- Serra-Crespo, P., Ramos-Fernandez, E. V., Gascon, J., & Kapteijn, F.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-04-26
- Volume
- 23
- Issue
- 10
- Pages
- 2565-2572
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2320627461
- Cited by
- 538
- References
- 43
- FWCI
- 26.04
- Type
- journal article
- Language
- en
- Open access
- closed
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