The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Manipulating the Morphology of P3HT–PCBM Bulk Heterojunction Blends with Solvent Vapor Annealing
Abstract
Using grazing incidence X-ray scattering, we observe the effects of solvent vapors upon the morphology of poly(3-hexylthiophene)–phenyl-C 61 -butyric acid methyl ester (P3HT–PCBM) bulk heterojunction thin film blends in real time; allowing us to observe morphological rearrangements that occur during this process as a function of solvent. We detail the swelling of the P3HT crystallites upon the introduction of solvent and the resulting changes in the P3HT crystallite morphology. We also demonstrate the ability for tetrahydrofuran vapor to induce crystallinity in PCBM domains. Additionally, we measure the nanoscale phase segregated domain size as a function of solvent vapor annealing and correlate this to the changes observed in the crystallite morphology of each component. Finally, we discuss the implications of the morphological changes induced by solvent vapor annealing on the device properties of BHJ solar cells.
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Cites
Nika : software for two-dimensional data reduction
Ilavsky, J. (2012) · Journal of Applied Crystallography · doi:10.1107/s0021889812004037 · Cited by 923
Cited by
Müller‐Buschbaum, P. (2014) · Advanced Materials · doi:10.1002/adma.201304187 · Cited by 730
Solvent Additives: Key Morphology‐Directing Agents for Solution‐Processed Organic Solar Cells
McDowell, C., Abdelsamie, M., Toney, M. F., & Bazan, G. C. (2018) · Advanced Materials · doi:10.1002/adma.201707114 · Cited by 513
Self-citationLi, S., Liu, W., Shi, M., Mai, J., Lau, T.-K., Wan, J., Lu, X., Li, C.-Z., & Chen, H. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03481g · Cited by 363
Pathway Complexity in π-Conjugated Materials
Korevaar, P. A., de Greef, T. F. A., & Meijer, E. W. (2014) · Chemistry of Materials · doi:10.1021/cm4021172 · Cited by 301
High-Efficiency Small Molecule-Based Bulk-Heterojunction Solar Cells Enhanced by Additive Annealing
Li, L., Xiao, L., Qin, H., Gao, K., Peng, J., Cao, Y., Liu, F., Russell, T. P., & Peng, X. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b06691 · Cited by 40
Low Energy Loss of 0.57 eV and High Efficiency of 8.80% in Porphyrin-Based BHJ Solar Cells
Vartanian, M., Singhal, R., de la Cruz, P., Biswas, S., Sharma, G. D., & Langa, F. (2018) · ACS Applied Energy Materials · doi:10.1021/acsaem.8b00024 · Cited by 19
Metadata
- Authors
- Verploegen, E., Miller, C. E., Schmidt, K., Bao, Z., & Toney, M. F.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-10-03
- Volume
- 24
- Issue
- 20
- Pages
- 3923-3931
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2318141565
- Cited by
- 196
- References
- 1
- FWCI
- 11.19
- Type
- journal article
- Language
- en
- Open access
- closed
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