The DOI matches its Crossref record; 53 of the 53 references it cites were found in a registry or an index.
Pathway Complexity in π-Conjugated Materials
Open accessAbstract
To arrive at functional organic materials with optimal molecular organization, control over the aggregation process is a prerequisite. Often, however, multiple pathways are involved that compete for the same molecular building block, a phenomenon known as pathway complexity. As a result, the material—made from small molecules or polymers—can get entrapped in a metastable pathway while a more stable but slower formed morphology is aimed for. Vice versa, the equilibrium state can be obtained easily, but another, less stable morphology is desired as it has more interesting properties. In both cases, the solution processing, starting from molecularly dissolved material, should be optimized to select the desired aggregation pathway. This Perspective aims to outline the importance of mechanistic insights derived from self-assembly of 1D fibers in diluted solutions to unravel and control aggregation pathways involved in the processing of π-conjugated materials.
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About Supramolecular Assemblies of π-Conjugated Systems
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Self-citationSolution-processed small-molecule solar cells with 6.7% efficiency
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Tuning charge transport in solution-sheared organic semiconductors using lattice strain
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Pathway complexity in supramolecular polymerization
Korevaar, P. A., George, S. J., Markvoort, A. J., Smulders, M. M. J., Hilbers, P. A. J., Schenning, A. P. H. J., De Greef, T. F. A., & Meijer, E. W. (2012) · Nature · doi:10.1038/nature10720 · Cited by 1,077
Self-citationSelf-Assembled Hexa- peri -hexabenzocoronene Graphitic Nanotube
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Cited by
Non-equilibrium supramolecular polymerization
Sorrenti, A., Leira-Iglesias, J., Markvoort, A. J., de Greef, T. F. A., & Hermans, T. M. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00121e · Cited by 574
Self-citationLiving Supramolecular Polymerization of a Perylene Bisimide Dye into Fluorescent J‐Aggregates
Wagner, W., Wehner, M., Stepanenko, V., Ogi, S., & Würthner, F. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201709307 · Cited by 212
A Bistable Switch in Dynamic Thiodepsipeptide Folding and Template‐Directed Ligation
Mukherjee, R., Cohen‐Luria, R., Wagner, N., & Ashkenasy, G. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201503898 · Cited by 46
Metadata
- Authors
- Korevaar, P. A., de Greef, T. F. A., & Meijer, E. W.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-09-12
- Volume
- 26
- Issue
- 1
- Pages
- 576-586
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2009828671
- Cited by
- 301
- References
- 53
- FWCI
- 6.47
- Type
- journal article
- Language
- en
- Open access
- green
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