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Water Sorption Cycle Measurements on Functionalized MIL-101Cr for Heat Transformation Application
Abstract
The water loading capacity and water cycle stability (40 adsorption/desorption cycles) of four nitro- or amino-functionalized MIL-101Cr materials ( 1 – 4 ) is assessed for heat transformation applications. Amino- or nitro-functionalized ( 1, 3 ) and partially amino- or nitro-functionalized MIL-101Cr ( 2, 4 ) have been synthesized through time-controlled postsynthetic modification of MIL-101Cr. The partially functionalized materials ( 2, 4 ) contain about 78 mol % amino- or nitro-functionalized terephthalate linker. Hydrophilic nitro or amino functionalities were introduced into MIL-101Cr in order to achieve water loading at lower p / p 0 values for possible use in thermally driven adsorption chillers or heat pumps. Among the four materials studied, fully aminated MIL-101Cr-NH 2, 1, and partially aminated MIL-101Cr-pNH 2, 2, showed the best water loadings (about 1.0 gH 2 O/gMIL) as well as water stability over 40 adsorption–desorption cycles. After 40 cycles, the X-ray powder diffractogram and Brunauer–Emmett–Teller (BET) surface determination of amino-functionalized materials indicated structural integrity with Δ BET = −6.3% after 40 cycles, while the nitro-functionalized MIL-101Cr exhibited a decrease in their BET surface of Δ BET = −25% and −20% for 3 and 4, respectively.
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Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
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Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
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Canivet, J., Fateeva, A., Guo, Y., Coasne, B., & Farrusseng, D. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00078a · Cited by 1,444
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Pore Chemistry of Metal–Organic Frameworks
Ji, Z., Wang, H., Canossa, S., Wuttke, S., & Yaghi, O. M. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202000238 · Cited by 459
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Rieth, A. J., Wright, A. M., & Dincă, M. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0140-1 · Cited by 402
Metadata
- Authors
- Khutia, A., Rammelberg, H. U., Schmidt, T., Henninger, S., & Janiak, C.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-02-26
- Volume
- 25
- Issue
- 5
- Pages
- 790-798
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2331550880
- Cited by
- 275
- References
- 1
- FWCI
- 34.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- Khutia, A., Rammelberg, H. U., Schmidt, T., Henninger, S., & Janiak, C. (2013). Water Sorption Cycle Measurements on Functionalized MIL-101Cr for Heat Transformation Application. Chemistry of Materials. https://doi.org/10.1021/cm304055k
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