Engineering Zeolites for Catalytic Cracking to Light Olefins
Abstract
Propene is a key building block for the petrochemical industry whose demand is increasing strongly in recent years, even faster than that of ethene. The availability of propene is limited, and therefore, efforts to optimize its production are being pursued. On the occasion of the 75th anniversary of the first FCC unit, we analyze some recent advances that have been achieved in the understanding and development of zeolites aiming to increase the production of light olefins as petrochemical building blocks by means of catalytic cracking. We discuss a selected group of emerging strategies in zeolite engineering that have great prospects for research and that we consider could impact the sector in the near future. These include advances in crystal engineering and hierarchization achieved through bottom-up and top-down approaches, composite materials, tuning of the location of active sites among the different crystallographic positions available, and, importantly, how to characterize these modifications and their impact on the catalysis. Finally, we survey what advances are actually being implanted into the current industrial practice and conclude with a reflection on the future of zeolite research to satisfy light olefin demand.
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Selectivity in many acid-catalyzed reactions by Al-containing zeolites strongly depends on the Al distribution in the zeolite framework.
“It has been found that selectivity in many acid-catalyzed reactions by Al-containing zeolites strongly depends on the Al distribution in the zeolite framework, which can be controlled by modifying the synthesis conditions.”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [148]
Al distribution in the zeolite framework can be controlled by modifying the synthesis conditions.
“It has been found that selectivity in many acid-catalyzed reactions by Al-containing zeolites strongly depends on the Al distribution in the zeolite framework, which can be controlled by modifying the synthesis conditions.”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [148]
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Narasimharao, K., & Alshehri, A. A. (2020) · Fuel · doi:10.1016/j.fuel.2020.118375 · Cited by 21 · see citing works
- Authors
- Blay, V., Louis, B., Miravalles, R., Yokoi, T., Peccatiello, K. A., Clough, M., & Yilmaz, B.
- Affiliations
- Universitat de València (ES)
- Centre National de la Recherche Scientifique (FR)
- Repsol (Spain) (ES)
- Tokyo Institute of Technology (JP)
- Peccatiello Engineering, Catalytic Cracking Solutions, LLC, Moriarity, New Mexico 87035, United States
- BASF Refinery Catalysts, 11750 Katy Fwy. Ste. 120, Houston, Texas 77079, United States
- BASF (United States) (US)
- Corresponding author
- Blay, Vincent
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-08-30
- Volume
- 7
- Issue
- 10
- Pages
- 6542-6566
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2745993733
- Cited by
- 277
- References
- 288
- Citations by year
- 2026: 32 · 2025: 34 · 2024: 38 · 2023: 36 · 2022: 38 · 2021: 37 · 2020: 21 · 2019: 21 · 2018: 19 · 2017: 1
- FWCI
- 6.49
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ACS Catalysis (publishedVersion)
- Funders
- Generalitat Valenciana
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Chemical Engineering › Catalysis › Catalysis and Oxidation Reactions
- Physical Sciences › Chemistry › Analytical Chemistry › Petroleum Processing and Analysis
- Keywords
- catalytic cracking, light olefins, propene production, fluid catalytic cracking, crystal engineering, hierarchical zeolites, zeolite composites, active site location, zeolite characterization
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