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Self-Assembled Hexa- peri -hexabenzocoronene Graphitic Nanotube
Abstract
An amphiphilic hexa- peri -hexabenzocoronene self-assembles to form a π-electronic, discrete nanotubular object. The object is characterized by an aspect ratio greater than 1000 and has a uniform, 14-nanometer-wide, open-ended hollow space, which is an order of magnitude larger than those of carbon nanotubes. The wall is 3 nanometers thick and consists of helical arrays of the π-stacked graphene molecule, whose exterior and interior surfaces are covered by hydrophilic triethylene glycol chains. The graphitic nanotube is redox active, and a single piece of the nanotube across 180-nanometer-gap electrodes shows, upon oxidation, an electrical conductivity of 2.5 megohms at 285 kelvin. This family of molecularly engineered graphite with a one-dimensional tubular shape and a chemically accessible surface constitutes an important step toward molecular electronics.
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Citations
Cited by
Yashima, E., Ousaka, N., Taura, D., Shimomura, K., Ikai, T., & Maeda, K. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00354 · Cited by 2,004
Self-assembled π-stacks of functional dyes in solution: structural and thermodynamic features
Chen, Z., Lohr, A., Saha-Möller, C. R., & Würthner, F. (2009) · Chem. Soc. Rev. · doi:10.1039/b809359h · Cited by 1,051
Challenges and breakthroughs in recent research on self-assembly
Ariga, K., Hill, J. P., Lee, M. V., Vinu, A., Charvet, R., & Acharya, S. (2008) · Science and Technology of Advanced Materials · doi:10.1088/1468-6996/9/1/014109 · Cited by 759
Self-citationFunctional Liquid Crystals towards the Next Generation of Materials
Kato, T., Uchida, J., Ichikawa, T., & Sakamoto, T. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201711163 · Cited by 518
Supramolecular Chemistry and Self-Assembly in Organic Materials Design
Stupp, S. I., & Palmer, L. C. (2014) · Chemistry of Materials · doi:10.1021/cm403028b · Cited by 513
Metadata
- Authors
- Hill, J. P., Jin, W., Kosaka, A., Fukushima, T., Ichihara, H., Shimomura, T., Ito, K., Hashizume, T., Ishii, N., & Aida, T.
- Venue
- Science
- Published
- 2004-06-04
- Volume
- 304
- Issue
- 5676
- Pages
- 1481-1483
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2020099789
- Cited by
- 1,053
- References
- 0
- FWCI
- 21.30
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hill, J. P., Jin, W., Kosaka, A., Fukushima, T., Ichihara, H., Shimomura, T., Ito, K., Hashizume, T., Ishii, N., & Aida, T. (2004). Self-Assembled Hexa- peri -hexabenzocoronene Graphitic Nanotube. Science. https://doi.org/10.1126/science.1097789
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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