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Nb-Doped Colloidal TiO2 Nanocrystals with Tunable Infrared Absorption
Open accessAbstract
We report a new colloidal synthesis of niobium-doped TiO 2 anatase nanocrystals (NCs) that allows for the preparation of ∼10 nm NCs with control over the amount of Nb doping up to ∼14%. The incorporation of niobium ions leads to the appearance of a tunable, broad absorption peak that ranges from the visible range to the mid-infrared. This optical behavior is attributed to the substitution of Nb 5+ on Ti 4+ sites generating free carriers inside the conduction band of the TiO 2 NCs as supported by optical and electron paramagnetic resonance spectroscopic investigations. At the same time, the incorporation of progressively more niobium ions drives an evolution of the shape of the NCs from tetragonal platelets to “peanutlike” rods.
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Cites
Aminolysis Route to Monodisperse Titania Nanorods with Tunable Aspect Ratio
Zhang, Z., Zhong, X., Liu, S., Li, D., & Han, M. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200500410 · Cited by 236
Cited by
Electrochromics for smart windows: Oxide-based thin films and devices
Granqvist, C. G. (2014) · Thin Solid Films · doi:10.1016/j.tsf.2014.02.002 · Cited by 1,080
Localized Surface Plasmon Resonance in Semiconductor Nanocrystals
Agrawal, A., Cho, S. H., Zandi, O., Ghosh, S., Johns, R. W., & Milliron, D. J. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00613 · Cited by 1,014
Self-citationLiu, X., & Swihart, M. T. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60417a · Cited by 428
Nonaqueous Chemistry of Group 4 Oxo Clusters and Colloidal Metal Oxide Nanocrystals
Van den Eynden, D., Pokratath, R., & De Roo, J. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c01008 · Cited by 83
Metadata
- Authors
- De Trizio, L., Buonsanti, R., Schimpf, A. M., Llordes, A., Gamelin, D. R., Simonutti, R., & Milliron, D. J.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-08-13
- Volume
- 25
- Issue
- 16
- Pages
- 3383-3390
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2323222189
- Cited by
- 190
- References
- 1
- FWCI
- 6.61
- Type
- journal article
- Language
- en
- Open access
- green
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- De Trizio, L., Buonsanti, R., Schimpf, A. M., Llordes, A., Gamelin, D. R., Simonutti, R., & Milliron, D. J. (2013). Nb-Doped Colloidal TiO2 Nanocrystals with Tunable Infrared Absorption. Chemistry of Materials. https://doi.org/10.1021/cm402396c
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