Cited by 236TiO2 Photocatalysis and Solar CellsMesoporous Materials and CatalysisChemical and Physical Properties of Materials

Aminolysis Route to Monodisperse Titania Nanorods with Tunable Aspect Ratio

Zhang, Zhihua, Zhong, Xinhua, Liu, Shuhua, Li, Dongfei, Han, Mingyong·2005·Angewandte Chemie International Edition

Abstract

High-temperature nonhydrolytic aminolysis has been developed as an approach to monodisperse titania nanocrystals by exploiting the chemical modification of reactive titanium isopropoxide with oleic acid as the chelating ligand. Its capabilities for the anisotropic growth of highly crystalline anatase titania nanocrystals (see picture) with controlled size and shape have been demonstrated.

Integrity signals

Registry

Crossref · 10.1002/anie.200500410

Cites

38 of 38 references verified0 citation errors · 0 not checkable

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  • Amide elimination facilitates controlled growth of nanostructures like titania nanorods through reaction of metal oleates with amines.

    “Amide elimination facilitates the controlled growth of nanostructures like titania nanorods through the reaction of metal oleates with amines [48] ((4) in Scheme 1).”

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Authors
Zhang, Z., Zhong, X., Liu, S., Li, D., & Han, M.
Affiliations
  • National University of Singapore (SG)
  • Institute of Materials Research and Engineering (SG)
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2005-05-24
Volume
44
Issue
22
Pages
3466-3470
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2104697120
Cited by
236
References
38
Citations by year
2026: 2 · 2025: 1 · 2024: 6 · 2023: 4 · 2022: 8 · 2021: 6 · 2020: 8 · 2019: 8 · 2018: 5 · 2017: 14 · 2016: 9 · 2015: 10 · 2014: 17 · 2013: 19 · 2012: 20
FWCI
10.49
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
  • National University of Singapore (submittedVersion)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
  • Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
  • Physical Sciences › Materials Science › Materials Chemistry › Chemical and Physical Properties of Materials
Keywords
titania nanorods, aminolysis, titanium isopropoxide, oleic acid, chelating ligands, anatase, monodisperse nanocrystals, aspect ratio control, anisotropic growth, crystallinity

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