The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.
Perovskites for Solar Thermoelectric Applications: A First Principle Study of CH3NH3AI3(A = Pb and Sn)
Abstract
Hybrid organic/inorganic CH 3 NH 3 AI 3 (A = Pb and Sn) perovskites have been recognized as promising photovoltaic materials. Using ab initio calculations, we showed that these systems may also be promising materials for solar thermoelectric applications. We found that their large carrier mobilities mainly originate from a combination of the small effective masses of electrons and holes and a relatively weak carrier–phonon interaction. We propose that by tuning the carrier concentration to values of the order of ∼10 18 cm –3, the thermoelectric figure of merit of Sn and Pb based perovskites may reach values ranging from 1 to 2, which could possibly be further increased by optimizing the lattice thermal conductivity through engineering perovskite superlattices.
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Cites
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Cited by
Lead iodide perovskite light-emitting field-effect transistor
Chin, X. Y., Cortecchia, D., Yin, J., Bruno, A., & Soci, C. (2015) · Nature Communications · doi:10.1038/ncomms8383 · Cited by 767
Yettapu, G. R., Talukdar, D., Sarkar, S., Swarnkar, A., Nag, A., Ghosh, P., & Mandal, P. (2016) · Nano Letters · doi:10.1021/acs.nanolett.6b01168 · Cited by 594
Leguy, A. M. A., Goñi, A. R., Frost, J. M., Skelton, J., Brivio, F., Rodríguez-Martínez, X., Weber, O. J., Pallipurath, A., Alonso, M. I., Campoy-Quiles, M., et al. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp03474h · Cited by 459
Optical phonons in methylammonium lead halide perovskites and implications for charge transport
Sendner, M., Nayak, P. K., Egger, D. A., Beck, S., Müller, C., Epding, B., Kowalsky, W., Kronik, L., Snaith, H. J., Pucci, A., et al. (2016) · Materials Horizons · doi:10.1039/c6mh00275g · Cited by 403
Effects of organic cations on the defect physics of tin halide perovskites
Shi, T., Zhang, H.-S., Meng, W., Teng, Q., Liu, M., Yang, X., Yan, Y., Yip, H.-L., & Zhao, Y.-J. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta02662e · Cited by 292
Metadata
- Authors
- He, Y., & Galli, G.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-08-29
- Volume
- 26
- Issue
- 18
- Pages
- 5394-5400
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2317859726
- Cited by
- 359
- References
- 37
- FWCI
- 16.08
- Type
- journal article
- Language
- en
- Open access
- closed
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- He, Y., & Galli, G. (2014). Perovskites for Solar Thermoelectric Applications: A First Principle Study of CH3NH3AI3(A = Pb and Sn). Chemistry of Materials. https://doi.org/10.1021/cm5026766
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