Optical phonons in methylammonium lead halide perovskites and implications for charge transport
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The measured optical phonon frequencies are used to determine the electron–phonon coupling and upper limits for charge carrier mobilities.
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The uncorrected dataset yields unphysical values of epsilon_DC and epsilon_infinity (approximately -13), whereas the corrected data produce values around 33, which are consistent with literature reports.
“As summarized in Table 1, the uncorrected dataset yields unphysical values of ε DC and ε ∞ (approximately 13), whereas the corrected data produce values around 33, which are consistent with literature reports [38,39,41].”
From Impact of Sub-picosecond Timing Errors on Complex Conductivity Extraction in Terahertz Time-Domain Spectroscopy of Ultrathin FAPbI3 Films (2026) · cites this paper as [39]
Table I and the Results (p. 4) report a static dielectric constant of 33.5 for MAPbI₃, supporting approximately 33 as a literature comparison for εDC. They report ε∞ as 5.0, not approximately 33, and do not compare corrected with uncorrected datasets or report an unphysical value near −13. (LLM, conf=0.87)
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- Authors
- Sendner, M., Nayak, P. K., Egger, D. A., Beck, S., Müller, C., Epding, B., Kowalsky, W., Kronik, L., Snaith, H. J., Pucci, A., & Lovrinčić, R.
- Affiliations
- Heidelberg University (DE)
- University of Oxford (GB)
- Weizmann Institute of Science (IL)
- Technische Universität Braunschweig (DE)
- Corresponding author
- Lovrinčić, Robert
- Venue
- Materials Horizons
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2016
- Volume
- 3
- Issue
- 6
- Pages
- 613-620
- ISSN
- 2051-6347 (ISSN-L)
- 2051-6355
- OpenAlex
- W2483648951
- Cited by
- 403
- References
- 69
- Citations by year
- 2026: 31 · 2025: 29 · 2024: 32 · 2023: 31 · 2022: 41 · 2021: 61 · 2020: 53 · 2019: 35 · 2018: 58 · 2017: 31 · 2016: 1
- FWCI
- 19.18
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- cc-by
- Locations
- Materials Horizons (publishedVersion, cc-by)
- arXiv (Cornell University) (submittedVersion)
- arXiv (Cornell University)
- Funders
- Bundesministerium für Bildung und Forschung (13N13656, 13N13657)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Perovskite Materials and Applications
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Magnetic and transport properties of perovskites and related materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Keywords
- optical phonons, methylammonium lead halide perovskites, electron-phonon coupling, carrier mobility, charge transport, phonon frequencies
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