The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Chloride in Lead Chloride-Derived Organo-Metal Halides for Perovskite-Absorber Solar Cells
Abstract
Organo-metal halide perovskites are an intriguing class of materials that have recently been explored for their potential in solar energy conversion. Within a very short period of intensive research, highly efficient solar cell devices have been demonstrated. One of the heavily debated questions in this new field of research concerns the role of chlorine in solution-processed samples utilizing lead chloride and 3 equiv of methylammonium iodide to prepare the perovskite samples. We utilized a combination of X-ray photoelectron spectroscopy, X-ray fluorescence, and X-ray diffraction to probe the amount of chlorine in samples before and during annealing. As-deposited samples, before annealing, consist of a crystalline precursor phase containing excess methylammonium and halide. We used in situ techniques to study the crystallization of MAPbI 3 from this crystalline precursor phase. Excess methylammonium and chloride evaporate during annealing, forming highly crystalline MAPbI 3 . However, even after prolonged annealing times, chlorine can be detected in the films in X-ray fluorescence measurements.
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Stranks, S. D., Eperon, G. E., Grancini, G., Menelaou, C., Alcocer, M. J. P., Leijtens, T., Herz, L. M., Petrozza, A., & Snaith, H. J. (2013) · Science · doi:10.1126/science.1243982 · Cited by 10,413
Kim, H.-S., Lee, C.-R., Im, J.-H., Lee, K.-B., Moehl, T., Marchioro, A., Moon, S.-J., Humphry-Baker, R., Yum, J.-H., Moser, J. E., et al. (2012) · Scientific Reports · doi:10.1038/srep00591 · Cited by 8,092
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Stranks, S. D., & Snaith, H. J. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.90 · Cited by 3,392
Synthetic Approaches for Halide Perovskite Thin Films
Dunlap-Shohl, W. A., Zhou, Y., Padture, N. P., & Mitzi, D. B. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00318 · Cited by 631
Progress on Perovskite Materials and Solar Cells with Mixed Cations and Halide Anions
Ono, L. K., Juarez-Perez, E. J., & Qi, Y. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b06001 · Cited by 593
The Importance of Moisture in Hybrid Lead Halide Perovskite Thin Film Fabrication
Eperon, G. E., Habisreutinger, S. N., Leijtens, T., Bruijnaers, B. J., van Franeker, J. J., deQuilettes, D. W., Pathak, S., Sutton, R. J., Grancini, G., Ginger, D. S., et al. (2015) · ACS Nano · doi:10.1021/acsnano.5b03626 · Cited by 574
Philippe, B., Park, B.-W., Lindblad, R., Oscarsson, J., Ahmadi, S., Johansson, E. M. J., & Rensmo, H. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b00348 · Cited by 462
Rationalization of passivation strategies toward high-performance perovskite solar cells
Zhang, Z., Qiao, L., Meng, K., Long, R., Chen, G., & Gao, P. (2023) · Chemical Society Reviews · doi:10.1039/d2cs00217e · Cited by 357
Sharenko, A., & Toney, M. F. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b10723 · Cited by 242
Self-citationMundt, L. E., & Schelhas, L. T. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903074 · Cited by 58
Elemental segregation and dimensional separation in halide perovskite light-emitting diodes
Yang, S. J., Lee, Y. H., Tateno, K., & Dou, L. (2024) · Progress in Quantum Electronics · doi:10.1016/j.pquantelec.2024.100537 · Cited by 10
Metadata
- Authors
- Unger, E. L., Bowring, A. R., Tassone, C. J., Pool, V. L., Gold-Parker, A., Cheacharoen, R., Stone, K. H., Hoke, E. T., Toney, M. F., & McGehee, M. D.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-12-12
- Volume
- 26
- Issue
- 24
- Pages
- 7158-7165
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2321512285
- Cited by
- 281
- References
- 2
- FWCI
- 21.93
- Type
- journal article
- Language
- en
- Open access
- closed
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