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MnO2-Based Nanostructures as Catalysts for Electrochemical Oxygen Reduction in Alkaline Media
Abstract
This paper reports a systematical study on the electrochemical properties of MnO 2 -based nanostructures as low-cost catalysts for oxygen reduction reaction (ORR) in alkaline media. The results show that the catalytic activities of MnO 2 depend strongly on the crystallographic structures, following an order of α- > β- > γ-MnO 2 . Meanwhile, morphology is another important influential factor to the electrochemical properties. Among various micro and nanostructures, α-MnO 2 nanospheres and nanowires outperform the counterpart microparticles. Furthermore, a new nanocomposite catalyst by depositing Ni nanoparticles on α-MnO 2 nanowires (denoted as MnO 2 -NWs@Ni-NPs) was prepared and characterized. The as-prepared MnO 2 -NWs@Ni-NPs nanocomposite exhibits an onset potential of 0.08 V, a specific current of 33.5 mA/mg, and an overall quasi 4-electron transfer involved in oxygen reduction reaction, indicating its potential application as the electrocatalyst of oxygen reduction reaction.
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Metadata
- Authors
- Cheng, F., Su, Y., Liang, J., Tao, Z., & Chen, J.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-11-17
- Volume
- 22
- Issue
- 3
- Pages
- 898-905
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2018359639
- Cited by
- 729
- References
- 4
- FWCI
- 10.91
- Type
- journal article
- Language
- en
- Open access
- closed
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