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Highly Visible Light Active TiO2−xNx Heterojunction Photocatalysts
Open accessAbstract
Nitrogen doped anatase-rutile heterojunctions are successfully synthesized through an ethylenediaminetetraacetic acid (EDTA) modified sol−gel process. An FT-IR study of EDTA modified TiO 2 gel confirms the existence of an ionic intermediate (as indicated by a Δν value of 233 cm −1 ). Differential scanning calorimetry (DSC), X-ray diffraction (XRD), and Raman spectroscopy are employed to study the phase evolution, phase purity, and crystallite size of samples. Formations of O−Ti−N and N−Ti−N bonds in calcined samples are confirmed using XPS and FT-IR spectroscopy. All EDTA modified samples show significantly higher visible light photocatalytic activity than the unmodified sample. The most active nitrogen doped heterojunction obtained at 400 °C exhibits 9-fold visible light activity in comparison to the standard photocatalyst Degussa P-25. It is proposed that the photo excited electrons (from the visible midgap level) are effectively transferred from the conduction band of anatase to that of rutile causing effective electron−hole separation, which is responsible for the higher visible light activity and lower photoluminescence (PL) intensity.
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Cites
Raman spectrum of anatase, TiO 2
Ohsaka, T., Izumi, F., & Fujiki, Y. (1978) · Journal of Raman Spectroscopy · doi:10.1002/jrs.1250070606 · Cited by 2,327
Cited by
A review on the visible light active titanium dioxide photocatalysts for environmental applications
Pelaez, M., Nolan, N. T., Pillai, S. C., Seery, M. K., Falaras, P., Kontos, A. G., Dunlop, P. S. M., Hamilton, J. W. J., Byrne, J. A., O'Shea, K., et al. (2012) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2012.05.036 · Cited by 4,047
Self-citationRecent advances in photocatalysis for environmental applications
Byrne, C., Subramanian, G., & Pillai, S. C. (2018) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2017.07.080 · Cited by 820
Self-citationNanoscale TiO2 films and their application in remediation of organic pollutants
Varshney, G., Kanel, S. R., Kempisty, D. M., Varshney, V., Agrawal, A., Sahle-Demessie, E., Varma, R. S., & Nadagouda, M. N. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.06.011 · Cited by 160
Metadata
- Authors
- Etacheri, V., Seery, M. K., Hinder, S. J., & Pillai, S. C.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-05-28
- Volume
- 22
- Issue
- 13
- Pages
- 3843-3853
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W1490542272
- Cited by
- 283
- References
- 1
- FWCI
- 8.89
- Type
- journal article
- Language
- en
- Open access
- green
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- Etacheri, V., Seery, M. K., Hinder, S. J., & Pillai, S. C. (2010). Highly Visible Light Active TiO2−xNx Heterojunction Photocatalysts. Chemistry of Materials. https://doi.org/10.1021/cm903260f
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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