Raman spectrum of anatase, TiO 2
Abstract
Raman spectra of anatase have been observed in natural and synthetic crystals. Both crystals show the same spectral features. The Raman band occurring at 516 cm −1 at room temperature is split into two peaks centred at 519 cm −1 and 513 cm −1 at low temperature (73 K). The six Raman active fundamentals predicted by group theory are all observed and assigned. The spectra are analyzed by a simple model considering only short‐range forces and the calculated vibrational frequencies are in good agreement with the observed Raman frequencies.
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Raman spectroscopy allowed identifying both anatase and TiO2(B) characteristic vibration modes.
“Raman spectroscopy (Fig. 6) allowed us to identify both anatase [30] and TiO2(B) [31] characteristic vibration modes.”
From Impact of three different TiO2 morphologies on hydrogen evolution by methanol assisted water splitting: Nanoparticles, nanotubes and aerogels (2011) · cites this paper as [30]
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- Authors
- Ohsaka, T., Izumi, F., & Fujiki, Y.
- Venue
- Journal of Raman Spectroscopy
- Publisher
- Wiley
- Published
- 1978-12
- Volume
- 7
- Issue
- 6
- Pages
- 321-324
- ISSN
- 0377-0486 (ISSN-L)
- 1097-4555
- OpenAlex
- W2088149984
- Cited by
- 2,327
- References
- 12
- Citations by year
- 2026: 124 · 2025: 113 · 2024: 113 · 2023: 96 · 2022: 102 · 2021: 121 · 2020: 136 · 2019: 162 · 2018: 152 · 2017: 163 · 2016: 135 · 2015: 123 · 2014: 116 · 2013: 98 · 2012: 101
- FWCI
- 1.90
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Raman Spectroscopy (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Biophysics › Spectroscopy Techniques in Biomedical and Chemical Research
- Physical Sciences › Materials Science › Materials Chemistry › Solid-state spectroscopy and crystallography
- Keywords
- anatase, titanium dioxide, Raman spectra, vibrational frequencies
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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