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Nonhydrolytic Sol−Gel Routes to Oxides
Abstract
This review surveys the chemistry of various nonhydrolytic sol−gel processes including hydroxylation in nonaqueous systems and aprotic condensation reactions. Some examples of applications in the field of single and multicomponent oxides demonstrate the interest of these approaches as alternatives to the usual hydrolytic routes. More particularly nonhydrolytic methods lead to improved control over the molecular level homogeneity and stoichiometry of multicomponent oxides.
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Cited by
Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks
Yang, P., Zhao, D., Margolese, D. I., Chmelka, B. F., & Stucky, G. D. (1998) · Nature · doi:10.1038/24132 · Cited by 2,493
The Evolution of “sol-Gel” Chemistry as a Technique for Materials Synthesis
Danks, A. E., Hall, S. R., & Schnepp, Z. (2016) · Materials Horizons · doi:10.1039/c5mh00260e · Cited by 1,718
Nonaqueous sol–gel routes to metal oxide nanoparticles
Niederberger, M. (2007) · Accounts of Chemical Research · doi:10.1021/ar600035e · Cited by 761
On the Synergetic Catalytic Effect in Heterogeneous Nanocomposite Catalysts
Shi, J. (2013) · Chemical Reviews · doi:10.1021/cr3002752 · Cited by 652
Multigram Scale Synthesis and Characterization of Monodisperse Tetragonal Zirconia Nanocrystals
Joo, J., Yu, T., Kim, Y. W., Park, H. M., Wu, F., Zhang, J. Z., & Hyeon, T. (2003) · Journal of the American Chemical Society · doi:10.1021/ja034258b · Cited by 412
Synthesis of TiO2 Nanocrystals by Nonhydrolytic Solution-Based Reactions
Trentler, T. J., Denler, T. E., Bertone, J. F., Agrawal, A., & Colvin, V. L. (1999) · Journal of the American Chemical Society · doi:10.1021/ja983361b · Cited by 382
Niederberger, M., Garnweitner, G., Pinna, N., & Antonietti, M. (2004) · Journal of the American Chemical Society · doi:10.1021/ja0494959 · Cited by 284
Near Monodisperse TiO2 Nanoparticles and Nanorods
Li, X., Peng, Q., Yi, J., Wang, X., & Li, Y. (2006) · Chemistry – A European Journal · doi:10.1002/chem.200500893 · Cited by 175
Non‐Aqueous Synthesis of High‐Purity Metal Oxide Nanopowders Using an Ether Elimination Process
Pinna, N., Garnweitner, G., Antonietti, M., & Niederberger, M. (2004) · Advanced Materials · doi:10.1002/adma.200400460 · Cited by 168
Tang, J., Fabbri, J., Robinson, R. D., Zhu, Y., Herman, I. P., Steigerwald, M. L., & Brus, L. E. (2004) · Chemistry of Materials · doi:10.1021/cm049945w · Cited by 154
Nonaqueous Chemistry of Group 4 Oxo Clusters and Colloidal Metal Oxide Nanocrystals
Van den Eynden, D., Pokratath, R., & De Roo, J. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c01008 · Cited by 83
Metadata
- Authors
- Vioux, A.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 1997-11-01
- Volume
- 9
- Issue
- 11
- Pages
- 2292-2299
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2051260051
- Cited by
- 474
- References
- 0
- FWCI
- 5.23
- Type
- journal article
- Language
- en
- Open access
- closed
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