The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
Production of Hollow Microspheres from Nanostructured Composite Particles
Abstract
Uniform inorganic and hybrid inorganic−organic hollow microspheres have been produced by coating colloidal core templates with alternating layers of oppositely charged nanoparticles and polymer, and thereafter removing the core either by heating or chemical treatment. The multilayers were constructed by consecutively depositing the nanoparticles and polymer onto the colloidal templates, utilizing the electrostatic attraction between the particles and polymer for layer build-up. Hollow silica spheres were obtained by calcining polymer latex spheres coated with multilayers of silica nanoparticles (SiO 2 ) bridged by polymer [poly(diallyldimethylammonium chloride) (PDADMAC)]. Exposure of SiO 2 /PDADMAC multilayer-coated polymer latex colloids to acidic solutions, dimethyl sulfoxide, or tetrahydrofuran yielded hollow composite silica−polymer spheres. The fabricated hollow spheres have been characterized using scanning and transmission electron microscopy. The approach employed is well suited to generating hollow spheres of controlled diameter, wall thickness, and composition.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Nanoengineering of Inorganic and Hybrid Hollow Spheres by Colloidal Templating
Caruso, F., Caruso, R. A., & Möhwald, H. (1998) · Science · doi:10.1126/science.282.5391.1111 · Cited by 4,135
Self-citationSynthesis of Nanosized Gold−Silica Core−Shell Particles
Liz-Marzán, L. M., Giersig, M., & Mulvaney, P. (1996) · Langmuir · doi:10.1021/la9601871 · Cited by 1,863
Novel Hollow Polymer Shells by Colloid-Templated Assembly of Polyelectrolytes
Donath, E., Sukhorukov, G. B., Caruso, F., Davis, S. A., & Möhwald, H. (1998) · Angewandte Chemie International Edition · doi:10.1002/(sici)1521-3773(19980904)37:16<2201::aid-anie2201>3.0.co;2-e · Cited by 1,861
Self-citationPhilipse, A. P., van Bruggen, M. P. B., & Pathmamanoharan, C. (1994) · Langmuir · doi:10.1021/la00013a014 · Cited by 568
Fabrication of hollow porous shells of calcium carbonate from self-organizing media
Walsh, D., & Mann, S. (1995) · Nature · doi:10.1038/377320a0 · Cited by 417
Magnetic Core-Shell Particles: Preparation of Magnetite Multilayers on Polymer Latex Microspheres
Caruso, F., Susha, A. S., Giersig, M., & Möhwald, H. (1999) · Advanced Materials · doi:10.1002/(sici)1521-4095(199908)11:11<950::aid-adma950>3.0.co;2-t · Cited by 338
Self-citationCorrea‐Duarte, M. A., Giersig, M., & Liz‐Marzán, L. M. (1998) · Chemical Physics Letters · doi:10.1016/s0009-2614(98)00012-8 · Cited by 319
Direct observation of chemical reactions in silica‐coated gold and silver nanoparticles
Mulvaney, P., Giersig, M., Ung, T., & Liz‐Marzán, L. M. (1997) · Advanced Materials · doi:10.1002/adma.19970090712 · Cited by 295
Double-walled polymer microspheres for controlled drug release
Pekarek, K. J., Jacob, J. S., & Mathiowitz, E. (1994) · Nature · doi:10.1038/367258a0 · Cited by 278
Preparation and properties of uniform coated colloidal particles. VII. Silica on hematite
Ohmori, M., & Matijević, E. (1992) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(92)90229-f · Cited by 272
Cited by
Polymer/Silica Nanocomposites: Preparation, Characterization, Properties, and Applications
Zou, H., Wu, S., & Shen, J. (2008) · Chemical Reviews · doi:10.1021/cr068035q · Cited by 2,121
Synthesis, Properties, and Applications of Hollow Micro-/Nanostructures
Wang, X., Feng, J., Bai, Y., Zhang, Q., & Yin, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00731 · Cited by 1,456
Ariga, K., Hill, J. P., & Ji, Q. (2007) · Physical Chemistry Chemical Physics · doi:10.1039/b700410a · Cited by 1,256
Organic Templates for the Generation of Inorganic Materials
van Bommel, K. J. C., Friggeri, A., & Shinkai, S. (2003) · Angewandte Chemie International Edition · doi:10.1002/anie.200390284 · Cited by 873
Chuang, C., Don, T., & Chiu, W. (2009) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.23564 · Cited by 69
Metadata
- Authors
- Caruso, F., Caruso, R. A., & Möhwald, H.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-10-13
- Volume
- 11
- Issue
- 11
- Pages
- 3309-3314
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2016340107
- Cited by
- 295
- References
- 11
- FWCI
- 6.86
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Production of Hollow Microspheres from Nanostructured Composite Particles. https://app.cochat.ai/papers/10.1021/cm991083p
- The paper
- Caruso, F., Caruso, R. A., & Möhwald, H. (1999). Production of Hollow Microspheres from Nanostructured Composite Particles. Chemistry of Materials. https://doi.org/10.1021/cm991083p
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.