The DOI matches its Crossref record; 146 of the 146 references it cites were found in a registry or an index.
Electron Transfer at Oxide Surfaces. The MgO Paradigm: from Defects to Ultrathin Films
Abstract
Electron transfer (ET) is a fundamental process in physics, chemistry, and biology. Charge transfer determines phenomena like oxidation and reduction, bond activation and bond breaking in chemical reactions, formation of radical species, and charge transport and charge trapping in nanoelectronic devices, just to mention a few examples. ET processes are the basis of technologically relevant fields. One of the best characterized systems is MgO, a simple stoichiometric binary oxide with rock-salt structure, which exhibits well-defined surfaces and is stable under operating conditions. Despite this apparent simplicity, a lot of work spanning several decades has been necessary to unravel the atomistic details of reactivity of this material. When going from a (001) single crystal surface, where the number of such sites is negligible, to a powder sample, where these sites represent a significant fraction of the total exposed surface, one observes a complete change of reactivity, from totally inert to highly reactive.
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Cites
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Cited by
Electrically-Transduced Chemical Sensors Based on Two-Dimensional Nanomaterials
Meng, Z., Stolz, R. M., Mendecki, L., & Mirica, K. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00311 · Cited by 773
Electronic interactions and charge transfers of metal atoms and clusters on oxide surfaces
Pacchioni, G. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp43731g · Cited by 272
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Metadata
- Authors
- Pacchioni, G., & Freund, H.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-11-01
- Volume
- 113
- Issue
- 6
- Pages
- 4035-4072
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2063179611
- Cited by
- 320
- References
- 146
- FWCI
- 1.00
- Type
- journal article
- Language
- en
- Open access
- closed
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