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Electron Transfer at Oxide Surfaces. The MgO Paradigm: from Defects to Ultrathin Films
Abstract
Electron transfer (ET) is a fundamental process in physics, chemistry, and biology. Charge transfer determines phenomena like oxidation and reduction, bond activation and bond breaking in chemical reactions, formation of radical species, and charge transport and charge trapping in nanoelectronic devices, just to mention a few examples. ET processes are the basis of technologically relevant fields. One of the best characterized systems is MgO, a simple stoichiometric binary oxide with rock-salt structure, which exhibits well-defined surfaces and is stable under operating conditions. Despite this apparent simplicity, a lot of work spanning several decades has been necessary to unravel the atomistic details of reactivity of this material. When going from a (001) single crystal surface, where the number of such sites is negligible, to a powder sample, where these sites represent a significant fraction of the total exposed surface, one observes a complete change of reactivity, from totally inert to highly reactive.
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The electronic structure of neutral and charged surface vacancy defects in periclase
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Photoreaction Dynamics of Molecular Adsorbates on Semiconductor and Oxide Surfaces
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Self-citation
Metadata
- Authors
- Pacchioni, G., & Freund, H.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-11-01
- Volume
- 113
- Issue
- 6
- Pages
- 4035-4072
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2063179611
- Cited by
- 320
- References
- 146
- FWCI
- 1.00
- Type
- journal article
- Language
- en
- Open access
- closed
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
