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Trinuclear Metallacycles: Metallatriangles and Much More
Abstract
This review article is intended to be a comprehensive, and yet critical, collection of the trinuclear metallacycles described to date. The main focus will be on the geometry of the metallacycles: the synthetic pathway leading to these species will not be used as a discriminating factor. In most cases, they were obtained (either on purpose or not) according to the principles of self-assembly, i.e., by the combination of metal fragments with two labile ligands (either with a trans or, more often, cis geometry) and ditopic linkers. However examples of trinuclear cyclic compounds obtained by different synthetic pathways (e.g., transformation of mononuclear metal complexes or metal-induced transfor- mation of added reagents) will be equally considered.
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Metadata
- Authors
- Zangrando, E., Casanova, M., & Alessio, E.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-12-10
- Volume
- 108
- Issue
- 12
- Pages
- 4979-5013
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2017042218
- Cited by
- 274
- References
- 28
- FWCI
- 0.94
- Type
- journal article
- Language
- en
- Open access
- closed
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