The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Aerobic Oxidation of Cyclohexane Catalyzed by Size-Controlled Au Clusters on Hydroxyapatite: Size Effect in the Sub-2 nm Regime
Abstract
In this work, we synthesized gold clusters, Au n ( n = 10, 18, 25, 39), with atomically controlled sizes on hydroxyapatite (HAP) and studied the catalysis for aerobic oxidation of cyclohexane. These Au n /HAP catalysts could efficiently oxidize cyclohexane to cyclohexanol and cyclohexanone. The turnover frequency monotonically increased with an increase in the size, reaching values as high as 18 500 h −1 Au atom −1 at n = 39, and thereafter decreased with a further increase in n up to n ∼ 85. This finding provides a fundamental insight into size-specific catalysis of gold in the cluster regime (diameter < 2 nm) and a guiding principle for rational design of Au cluster-based catalysts.
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Cites
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Selective oxidation with dioxygen by gold nanoparticle catalysts derived from 55-atom clusters
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On the origin of the catalytic activity of gold nanoparticles for low-temperature CO oxidation
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Switching Off Hydrogen Peroxide Hydrogenation in the Direct Synthesis Process
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Cyclohexane oxidation continues to be a challenge
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Selective oxidation using gold
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Self-citationCatalysis Applications of Size-Selected Cluster Deposition
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The effect of coordination environment on the activity and selectivity of single-atom catalysts
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Metadata
- Authors
- Liu, Y., Tsunoyama, H., Akita, T., Xie, S., & Tsukuda, T.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-12-10
- Volume
- 1
- Issue
- 1
- Pages
- 2-6
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2326481964
- Cited by
- 419
- References
- 27
- FWCI
- 13.28
- Type
- journal article
- Language
- en
- Open access
- closed
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