The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Aerobic Oxidation of Benzylic Alcohols Catalyzed by Metal−Organic Frameworks Assisted by TEMPO
Open accessAbstract
Cu 3 (BTC) 2 (BTC: 1,3,5-benzenetricarboxylate) combined with TEMPO as cocatalyst is an effective and reusable heterogeneous catalyst to effect the aerobic oxidation of benzylic alcohols in acetonitrile to the corresponding benzaldehydes under mild temperature at atmospheric pressure. The main deactivation process was attributed to the formation of carboxylic acids arising from the overoxidation of the aromatic aldehyde acting as poisons, coordinating to the free Cu(II) sites and blocking the pores. Comparison with copper acetate as a soluble, homogeneous system established that immobilization of the Cu(II) in the rigid crystal structure of Cu 3 (BTC) 2 does not diminish the intrinsic catalytic activity of this transition metal ion.
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Cites
Multicopper oxidases and oxygenases
Solomon, E. I., Sundaram, U. M., & Machonkin, T. E. (1996) · Chemical Reviews · doi:10.1021/cr950046o · Cited by 3,664
Supported gold nanoparticles as catalysts for organic reactions
Corma, A., & Garcia, H. (2008) · Chemical Society Reviews · doi:10.1039/b707314n · Cited by 1,883
Cited by
Aerobic Copper-Catalyzed Organic Reactions
Allen, S. E., Walvoord, R. R., Padilla-Salinas, R., & Kozlowski, M. C. (2013) · Chemical Reviews · doi:10.1021/cr300527g · Cited by 1,621
Commercial metal–organic frameworks as heterogeneous catalysts
Dhakshinamoorthy, A., Alvaro, M., & Garcia, H. (2012) · Chemical Communications · doi:10.1039/c2cc34329k · Cited by 422
Self-citationTanaka, A., Hashimoto, K., & Kominami, H. (2012) · Journal of the American Chemical Society · doi:10.1021/ja305225s · Cited by 398
Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals
Dhakshinamoorthy, A., Opanasenko, M., Čejka, J., & Garcia, H. (2013) · Catalysis Science & Technology · doi:10.1039/c3cy00350g · Cited by 296
Self-citationReusable Oxidation Catalysis Using Metal-Monocatecholato Species in a Robust Metal–Organic Framework
Fei, H., Shin, J., Meng, Y. S., Adelhardt, M., Sutter, J., Meyer, K., & Cohen, S. M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja411627z · Cited by 286
Metadata
- Authors
- Dhakshinamoorthy, A., Alvaro, M., & Garcia, H.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-12-17
- Volume
- 1
- Issue
- 1
- Pages
- 48-53
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W112633179
- Cited by
- 251
- References
- 2
- FWCI
- 7.42
- Type
- journal article
- Language
- en
- Open access
- green
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