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Supported Cobalt Oxide Nanoparticles As Catalyst for Aerobic Oxidation of Alcohols in Liquid Phase

Zhu, Junjiang, Kailasam, Kamalakannan, Fischer, Anna, Thomas, Arne·2011·ACS Catalysis

Abstract

Supported cobalt oxide nanoparticles (NPs) have been prepared by wetness impregnation on different supports and subsequent heat treatment in argon at 350 °C for 2 h. The thus prepared cobalt oxide (Co 3 O 4 ) can be well dispersed on carbonaceous materials such as activated carbon (AC) and covalent trizaine frameworks (CTF), with average particle sizes below 5 nm. The catalytic performance of supported Co 3 O 4 NPs was tested by aerobic oxidation of alcohols in liquid phase. The results show that AC supported Co 3 O 4 NPs, Co 3 O 4 /AC, exhibit ∼100% conversions for alcohol oxidation and can be reused for at least 4 runs without appreciable loss of activity, when a thermal regeneration step is carried out, suggesting that the Co 3 O 4 NPs are well embedded and stabilized on the support, making Co 3 O 4 /AC a promising catalyst for aerobic oxidation of alcohols in liquid phase.

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Metadata

Authors
Zhu, J., Kailasam, K., Fischer, A., & Thomas, A.
Venue
ACS Catalysis
Published
2011-03-02
Volume
1
Issue
4
Pages
342-347
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2317294870
Cited by
206
References
0
FWCI
4.34
Type
journal article
Language
en
Open access
closed

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Zhu, J., Kailasam, K., Fischer, A., & Thomas, A. (2011). Supported Cobalt Oxide Nanoparticles As Catalyst for Aerobic Oxidation of Alcohols in Liquid Phase. ACS Catalysis. https://doi.org/10.1021/cs100153a

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