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Cu-Based Catalysts Show Low Temperature Activity for Glycerol Conversion to Lactic Acid
Abstract
Cu based catalysts with a base promoter are reported for the first time for the synthesis of lactic acid from glycerol without using either a reductant or an oxidant. The catalytic route presented here gives high yields at lower temperatures (473 K) and lower molar NaOH/glycerol ratios (1.5) compared to the known hydrothermal (553−573 K) route. Further, the Cu 2 O catalyst shows excellent recyclability.
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Citations
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Bozell, J. J., & Petersen, G. R. (2010) · Green Chemistry · doi:10.1039/b922014c · Cited by 4,566
Cited by
Lactic acid as a platform chemical in the biobased economy: the role of chemocatalysis
Dusselier, M., Van Wouwe, P., Dewaele, A., Makshina, E., & Sels, B. F. (2013) · Energy & Environmental Science · doi:10.1039/c3ee00069a · Cited by 827
Glycerol hydrogenolysis into useful C3 chemicals
Sun, D., Yamada, Y., Sato, S., & Ueda, W. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.04.013 · Cited by 313
Phenomena Affecting Catalytic Reactions at Solid–Liquid Interfaces
Sievers, C., Noda, Y., Qi, L., Albuquerque, E. M., Rioux, R. M., & Scott, S. L. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02532 · Cited by 288
Efficient selective and atom economic catalytic conversion of glycerol to lactic acid
Sharninghausen, L. S., Campos, J., Manas, M. G., & Crabtree, R. H. (2014) · Nature Communications · doi:10.1038/ncomms6084 · Cited by 271
Recent Advances in Catalytic Conversion of Glycerol
Zhou, C. H., Zhao, H., Tong, D. S., Wu, L. M., & Yu, W. H. (2013) · Catalysis Reviews · doi:10.1080/01614940.2013.816610 · Cited by 200
Metadata
- Authors
- Roy, D., Subramaniam, B., & Chaudhari, R. V.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-04-13
- Volume
- 1
- Issue
- 5
- Pages
- 548-551
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2335706277
- Cited by
- 175
- References
- 1
- FWCI
- 5.11
- Type
- journal article
- Language
- en
- Open access
- closed
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- Roy, D., Subramaniam, B., & Chaudhari, R. V. (2011). Cu-Based Catalysts Show Low Temperature Activity for Glycerol Conversion to Lactic Acid. ACS Catalysis. https://doi.org/10.1021/cs200080j
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
