Recent Advances in Catalytic Conversion of Glycerol
Abstract
The article underlines and discusses the state-of-the-art accomplishments in the catalytic conversion of glycerol (1,2,3-propanetriol) to fuels and value-added chemicals in the past five years (2008–2012). The reactions include steam reforming, aqueous-phase reforming, hydrogenolysis, oxidation, dehydration, esterification, etherification, carboxylation, acetalization, and chlorination. Typical products are hydrogen, propanediols, dihydroxyacetone, glyceric acid, acrolein, glyceride, polyglycerol, glycerol carbonate, acetals, ketals, and epichlorohydrine. Recent studies on the catalysts, reaction conditions, and possible pathways are primarily discussed. They indicate that major breakthroughs are achieved by the use of multifunctional catalysts, process intensification and integrated reactions. Literature survey suggests that future work on the catalytic conversion of glycerol for commercial goals particularly requires new catalysts, innovative reactor engineering, and close multidisciplinary partnership.
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Epichlorohydrin (ECH), an important industrial chemical produced on a 1.8 million tons scale annually, can be derived from glycerin through a two-step reaction.
“Epichlorohydrin (ECH), an important industrial chemical produced on a 1.8 million tons scale annually, can be derived from glycerin through a two-step reaction.208,209”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [209]
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Catalysis as an Enabling Science for Sustainable Polymers
Zhang, X., Fevre, M., Jones, G. O., & Waymouth, R. M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00329 · Cited by 936 · see citing works
- Authors
- Zhou, C. H., Zhao, H., Tong, D. S., Wu, L. M., & Yu, W. H.
- Affiliations
- Zhejiang University of Technology (CN)
- Corresponding author
- Zhou, Chun Hui
- Venue
- Catalysis Reviews
- Publisher
- Informa UK Limited
- Published
- 2013-10-02
- Volume
- 55
- Issue
- 4
- Pages
- 369-453
- ISSN
- 0161-4940 (ISSN-L)
- 1520-5703
- OpenAlex
- W2015144962
- Cited by
- 200
- References
- 397
- Citations by year
- 2026: 7 · 2025: 9 · 2024: 10 · 2023: 8 · 2022: 14 · 2021: 10 · 2020: 17 · 2019: 16 · 2018: 12 · 2017: 31 · 2016: 22 · 2015: 20 · 2014: 24
- FWCI
- 12.14
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Catalysis Reviews (publishedVersion)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Catalysis for Biomass Conversion
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Synthesis and Reactions
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- glycerol, catalytic conversion, steam reforming, aqueous phase reforming, hydrogenolysis, glycerol oxidation, dehydration, esterification, etherification, carboxylation, acetalization, chlorination, multifunctional catalysts, process intensification, hydrogen production, propanediol, dihydroxyacetone, glyceric acid, acrolein, polyglycerol, glycerol carbonate, epichlorohydrin, acetals, ketals
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