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Zeolitic Imidazole Framework-8 Catalysts in the Conversion of CO2 to Chloropropene Carbonate
Abstract
The catalytic activity of zeolitic imidazole framework-8 (ZIF-8) and amine-functionalized ZIF-8 catalysts in the synthesis of chloropropene carbonate from CO 2 and epichlorohydrin is demonstrated. In contrast to hitherto known catalysts, ZIF-8 catalysts displayed high epoxide conversions and moderate to high selectivities to chloropropene carbonate at reaction temperatures as low as 70 °C. No cocatalysts or solvents were required during the reaction. The incorporation of ethylenediamine in ZIF-8 enhanced its catalytic performance as a result of the higher CO 2 adsorption capacity of the amine-functionalized samples. The ZIF-8 catalysts, however, lost their distinctive crystalline structure and superior catalytic performance when attempts were made to recycle them after use.
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Cited by
Yang, Q., Yang, C., Lin, C., & Jiang, H. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201813494 · Cited by 624
Sharma, R. K., Yadav, P., Yadav, M., Gupta, R., Rana, P., Srivastava, A., Zbořil, R., Varma, R. S., Antonietti, M., & Gawande, M. B. (2020) · Materials Horizons · doi:10.1039/c9mh00856j · Cited by 455
Metal organic framework based catalysts for CO2 conversion
Maina, J. W., Pozo-Gonzalo, C., Kong, L., Schütz, J., Hill, M., & Dumée, L. F. (2017) · Materials Horizons · doi:10.1039/c6mh00484a · Cited by 423
Recent advances in the synthesis of cyclic carbonates via CO2 cycloaddition to epoxides
Rehman, A., Saleem, F., Javed, F., Ikhlaq, A., Ahmad, S. W., & Harvey, A. (2021) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2021.105113 · Cited by 281
Formation of CX Bonds in CO2 Chemical Fixation Catalyzed by Metal−Organic Frameworks
Hou, S., Dong, J., & Zhao, B. (2020) · Advanced Materials · doi:10.1002/adma.201806163 · Cited by 142
Metadata
- Authors
- Miralda, C. M., Macias, E. E., Zhu, M., Ratnasamy, P., & Carreon, M. A.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-12-27
- Volume
- 2
- Issue
- 1
- Pages
- 180-183
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2026842054
- Cited by
- 468
- References
- 0
- FWCI
- 8.43
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Zeolitic Imidazole Framework-8 Catalysts in the Conversion of CO2 to Chloropropene Carbonate. https://app.cochat.ai/papers/10.1021/cs200638h
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- Miralda, C. M., Macias, E. E., Zhu, M., Ratnasamy, P., & Carreon, M. A. (2012). Zeolitic Imidazole Framework-8 Catalysts in the Conversion of CO2 to Chloropropene Carbonate. ACS Catalysis. https://doi.org/10.1021/cs200638h
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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