The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Zeolitic Imidazole Framework-8 Catalysts in the Conversion of CO2 to Chloropropene Carbonate
Abstract
The catalytic activity of zeolitic imidazole framework-8 (ZIF-8) and amine-functionalized ZIF-8 catalysts in the synthesis of chloropropene carbonate from CO 2 and epichlorohydrin is demonstrated. In contrast to hitherto known catalysts, ZIF-8 catalysts displayed high epoxide conversions and moderate to high selectivities to chloropropene carbonate at reaction temperatures as low as 70 °C. No cocatalysts or solvents were required during the reaction. The incorporation of ethylenediamine in ZIF-8 enhanced its catalytic performance as a result of the higher CO 2 adsorption capacity of the amine-functionalized samples. The ZIF-8 catalysts, however, lost their distinctive crystalline structure and superior catalytic performance when attempts were made to recycle them after use.
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Cites
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Self-citationAmino-Functionalized SAPO-34 Membranes for CO2/CH4 and CO2/N2 Separation
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Cited by
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Metal–organic frameworks for the chemical fixation of CO2 into cyclic carbonates
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Metadata
- Authors
- Miralda, C. M., Macias, E. E., Zhu, M., Ratnasamy, P., & Carreon, M. A.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-12-27
- Volume
- 2
- Issue
- 1
- Pages
- 180-183
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2026842054
- Cited by
- 468
- References
- 18
- FWCI
- 8.43
- Type
- journal article
- Language
- en
- Open access
- closed
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