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Cited by 829

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Two Different Roles of Metallic Ag on Ag/AgX/BiOX (X = Cl, Br) Visible Light Photocatalysts: Surface Plasmon Resonance and Z-Scheme Bridge

Ye, Liqun, Liu, Jinyan, Gong, Chuqing, Tian, Lihong, Peng, Tianyou, Zan, Ling·2012·ACS Catalysis

Abstract

Ag/AgX/BiOX (X = Cl, Br) three-component visible-light-driven (VLD) photocatalysts were synthesized by a low-temperature chemical bath method and characterized by X-ray diffraction patterns, X-ray photoelectron spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, and UV–vis diffuse reflectance spectra. The Ag/AgX/BiOX composites showed enhanced VLD photocatalytic activity for the degradation of rhodamine B, which was much higher than Ag/AgX and BiOX. The photocatalytic mechanisms were analyzed by active species trapping and superoxide radical quantification experiments. It revealed that metallic Ag played a different role for Ag/AgX/BiOX VLD photocatalysts, surface plasmon resonance for Ag/AgCl/BiOCl, and the Z-scheme bridge for Ag/AgBr/BiOBr.

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Metadata

Authors
Ye, L., Liu, J., Gong, C., Tian, L., Peng, T., & Zan, L.
Venue
ACS Catalysis
Published
2012-07-13
Volume
2
Issue
8
Pages
1677-1683
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2312716509
Cited by
829
References
1
FWCI
23.32
Type
journal article
Language
en
Open access
closed

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