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Synthesis, Characterization, and Photocatalytic Activity of Y-Doped CeO2 Nanorods
Abstract
Yttrium-doped ceria (YDC) nanorods were prepared by hydrothermal synthesis and characterized using Raman, UV–vis, transmission electron microscopy, scanning electron microscopy/energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and X-ray powder diffraction. The ceria nanorods showed an increase in the amount of oxygen vacancies with an increase in the Y concentration. When the doping level is <30%, the optical band gap of the doped ceria is lower than that of pure ceria nanorods. At < 50% of Y doping, the composite nanorods exhibited a higher photocatalytic activity for the degradation of model organic dyes compared to the pure ceria at room temperature, and the catalyst with 10% loading showed the maximum photocatalytic efficiency. However, at 100 °C, the photocatalytic activity significantly improved for all the nanorods with different Y loadings, and the greatest improvement was obtained for the sample with the highest number of oxygen vacancies.
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Environmental applications of semiconductor photocatalysis
Hoffmann, M. R., Martin, S. T., Choi, W., & Bahnemann, D. W. (1995) · Chemical Reviews · doi:10.1021/cr00033a004 · Cited by 18,495
Cited by
Fundamentals and Catalytic Applications of CeO 2 -Based Materials
Montini, T., Melchionna, M., Monai, M., & Fornasiero, P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00603 · Cited by 2,766
Liu, B., Li, C., Zhang, G., Yao, X., Chuang, S. S. C., & Li, Z. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b00415 · Cited by 668
Ma, R., Jahurul Islam, M., Amaranatha Reddy, D., & Kim, T. K. (2016) · Ceramics International · doi:10.1016/j.ceramint.2016.08.186 · Cited by 137
Xie, H., Wang, H., Geng, Q., Xing, Z., Wang, W., Chen, J., Ji, L., Chang, L., Wang, Z., & Mao, J. (2019) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.9b00622 · Cited by 112
Metadata
- Authors
- Liyanage, A. D., Perera, S. D., Tan, K., Chabal, Y., & Balkus, K. J.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-01-16
- Volume
- 4
- Issue
- 2
- Pages
- 577-584
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W1983889489
- Cited by
- 370
- References
- 1
- FWCI
- 9.61
- Type
- journal article
- Language
- en
- Open access
- closed
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