Fundamentals and Catalytic Applications of CeO 2 -Based Materials

Montini, Tiziano; Melchionna, Michele; Monai, Matteo; Fornasiero, Paolo

doi:10.1021/acs.chemrev.5b00603

Cited by 2,766Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsCatalysts for Methane Reforming

Fundamentals and Catalytic Applications of CeO 2 -Based Materials

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Montini, Tiziano, Melchionna, Michele, Monai, Matteo, Fornasiero, Paolo·2016·Chemical Reviews

DOI 10.1021/acs.chemrev.5b00603

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Abstract

Cerium dioxide (CeO2, ceria) is becoming an ubiquitous constituent in catalytic systems for a variety of applications. 2016 sees the 40(th) anniversary since ceria was first employed by Ford Motor Company as an oxygen storage component in car converters, to become in the years since its inception an irreplaceable component in three-way catalysts (TWCs). Apart from this well-established use, ceria is looming as a catalyst component for a wide range of catalytic applications. For some of these, such as fuel cells, CeO2-based materials have almost reached the market stage, while for some other catalytic reactions, such as reforming processes, photocatalysis, water-gas shift reaction, thermochemical water splitting, and organic reactions, ceria is emerging as a unique material, holding great promise for future market breakthroughs. While much knowledge about the fundamental characteristics of CeO2-based materials has already been acquired, new characterization techniques and powerful theoretical methods are deepening our understanding of these materials, helping us to predict their behavior and application potential. This review has a wide view on all those aspects related to ceria which promise to produce an important impact on our life, encompassing fundamental knowledge of CeO2 and its properties, characterization toolbox, emerging features, theoretical studies, and all the catalytic applications, organized by their degree of establishment on the market.

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Authors: Montini, T., Melchionna, M., Monai, M., & Fornasiero, P.
Affiliations: University of Trieste (IT)
Corresponding author: Fornasiero, Paolo
ORCID: Montini, Tiziano
Melchionna, Michele
Monai, Matteo
Fornasiero, Paolo
Venue: Chemical Reviews
Publisher: American Chemical Society (ACS)
Published: 2016-04-27
Volume: 116
Issue: 10
Pages: 5987-6041
ISSN: 0009-2665 (ISSN-L)
1520-6890
DOI: 10.1021/acs.chemrev.5b00603
OpenAlex: W2342691188
Cited by: 2,766
References: 656
Citations by year: 2026: 320 · 2025: 301 · 2024: 298 · 2023: 271 · 2022: 275 · 2021: 321 · 2020: 318 · 2019: 232 · 2018: 243 · 2017: 145 · 2016: 42
FWCI: 8.83
Type: journal article
Language: en
Open access: green
pubs.acs.org
Licence: other-oa
Locations: Chemical Reviews (publishedVersion)
PubMed (publishedVersion)
ArTS Archivio della ricerca di Trieste (University of Trieste https://www.units.it/) (submittedVersion, other-oa)
Funders: Seventh Framework Programme (310651)
Ministero dell'Istruzione, dell'Università e della Ricerca (2010N3T9M4)
Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali
Istituto di Chimica dei Composti OrganoMetallici, Consiglio Nazionale delle Ricerche
Topics: Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
Physical Sciences › Materials Science › Materials Chemistry › Advancements in Solid Oxide Fuel Cells
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Keywords: cerium oxide, three-way catalyst, oxygen storage, automotive exhaust aftertreatment, fuel cells, reforming, photocatalysis, water-gas shift reaction, thermochemical water splitting, organic reactions, catalytic materials, characterization techniques, theoretical analysis

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