The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Catalytic Conversion of Fructose, Glucose, and Sucrose to 5-(Hydroxymethyl)furfural and Levulinic and Formic Acids in γ-Valerolactone As a Green Solvent
Abstract
The conversion of fructose, glucose, and sucrose to 5-(hydroxymethyl)furfural (HMF) and levulinic acid (LA)/formic acid (FA) was investigated in detail using sulfuric acid as the catalyst and γ-valerolactone (GVL) as a green solvent. The H 2 SO 4 /GVL/H 2 O system can be tuned to produce either HMF or LA/FA by changing the acid concentration and thus allowing selective switching between the products. Although the best yields of HMF were around 75%, the LA/FA yields ranged from 50% to 70%, depending on the structure of the carbohydrates and the reaction parameters, including temperature, acid, and carbohydrate concentrations. While the conversion of fructose is much faster than glucose, sucrose behaves like a 1:1 mixture of fructose and glucose, indicating facile hydrolysis of the glycosidic bond in sucrose. The mechanism of the conversion of glucose to HMF or LA/FA in GVL involves three intermediates: 1,6-anhydro-β- d -glucofuranose, 1,6-anhydro-β- d -glucopyranose, and levoglucosenone.
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Cites
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013) · Chemical Reviews · doi:10.1021/cr300182k · Cited by 2,886
Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural
Zhao, H., Holladay, J. E., Brown, H., & Zhang, Z. C. (2007) · Science · doi:10.1126/science.1141199 · Cited by 1,997
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Deng, W., Feng, Y., Fu, J., Guo, H., Guo, Y., Han, B., Jiang, Z., Kong, L., Li, C., Liu, H., et al. (2023) · Green Energy & Environment · doi:10.1016/j.gee.2022.07.003 · Cited by 854
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Catalytic reactions of gamma-valerolactone: A platform to fuels and value-added chemicals
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Solvent Effects in Acid‐Catalyzed Biomass Conversion Reactions
Mellmer, M. A., Sener, C., Gallo, J. M. R., Luterbacher, J. S., Alonso, D. M., & Dumesic, J. A. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408359 · Cited by 451
Organic Solvent Effects in Biomass Conversion Reactions
Shuai, L., & Luterbacher, J. (2016) · ChemSusChem · doi:10.1002/cssc.201501148 · Cited by 445
Dutta, S., Yu, I. K. M., Tsang, D. C. W., Ng, Y. H., Ok, Y. S., Sherwood, J., & Clark, J. H. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.04.199 · Cited by 425
Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials
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Song, B., Lin, R., Lam, C. H., Wu, H., Tsui, T.-H., & Yu, Y. (2021) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2020.110370 · Cited by 186
Metadata
- Authors
- Qi, L., Mui, Y. F., Lo, S. W., Lui, M. Y., Akien, G. R., & Horváth, I. T.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-04-10
- Volume
- 4
- Issue
- 5
- Pages
- 1470-1477
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2330618456
- Cited by
- 307
- References
- 2
- FWCI
- 17.88
- Type
- journal article
- Language
- en
- Open access
- closed
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