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Cited by 241

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Supported Single Pt1/Au1 Atoms for Methanol Steam Reforming

Gu, Xiang-Kui, Qiao, Botao, Huang, Chuan-Qi, Ding, Wu-Chen, Sun, Keju, Zhan, Ensheng, Zhang, Tao, Liu, Jingyue, Li, Wei-Xue·2014·ACS Catalysis

Abstract

The single Pt 1 and Au 1 atoms stabilized by lattice oxygen on ZnO{10 1 0} surface for methanol steam reforming is reported. Density functional theory calculations reveal that the catalysis of the single precious metal atoms together with coordinated lattice oxygen stems from its stronger binding toward the intermediates, lowering reaction barriers, changing on the reaction pathway, enhancing greatly the activity. The measured turnover frequency of single Pt 1 sites was more than 1000 times higher than the pristine ZnO. The results provide valuable insights for the catalysis of the atomically dispersed precious metals on oxide supports.

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Crossref · 10.1021/cs500740u

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Metadata

Authors
Gu, X.-K., Qiao, B., Huang, C.-Q., Ding, W.-C., Sun, K., Zhan, E., Zhang, T., Liu, J., & Li, W.-X.
Venue
ACS Catalysis
Published
2014-10-03
Volume
4
Issue
11
Pages
3886-3890
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2325095228
Cited by
241
References
1
FWCI
4.20
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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