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Continuous DMC Synthesis from CO2 and Methanol over a CeO2 Catalyst in a Fixed Bed Reactor in the Presence of a Dehydrating Agent
Abstract
Methanol and carbon dioxide are continuously and efficiently converted to dimethyl carbonate (DMC) over a CeO 2 catalyst using 2-cyanopyridine as a recyclable dehydrating agent in a fixed bed reactor. The process was operated over a wide range of pressure (1–300 bar) by feeding CO 2 and the stoichiometric amount of methanol and 2-cyanopyridine mixture into the reactor. The study shows a successful demonstration of direct DMC synthesis mediated by a dehydrating agent with outstanding methanol conversion (>95%) and dimethyl carbonate selectivity (>99%) under optimized conditions. Remarkably higher reaction rates were achieved compared to those in batch operation.
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Cites
Shaikh, A.-A. G., & Sivaram, S. (1996) · Chemical Reviews · doi:10.1021/cr950067i · Cited by 1,381
Choi, J.-C., Kohno, K., Ohshima, Y., Yasuda, H., & Sakakura, T. (2008) · Catalysis Communications · doi:10.1016/j.catcom.2008.01.013 · Cited by 84
Cited by
Liu, B., Li, C., Zhang, G., Yao, X., Chuang, S. S. C., & Li, Z. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b00415 · Cited by 668
Trends in CO2 conversion and utilization: A review from process systems perspective
Rafiee, A., Rajab Khalilpour, K., Milani, D., & Panahi, M. (2018) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2018.08.065 · Cited by 435
Carbon capture and utilization technologies: a literature review and recent advances
Baena-Moreno, F. M., Rodríguez-Galán, M., Vega, F., Alonso-Fariñas, B., Vilches Arenas, L. F., & Navarrete, B. (2019) · Energy Sources, Part A: Recovery, Utilization, and Environmental Effects · doi:10.1080/15567036.2018.1548518 · Cited by 351
Direct Copolymerization of CO2 and Diols
Tamura, M., Ito, K., Honda, M., Nakagawa, Y., Sugimoto, H., & Tomishige, K. (2016) · Scientific Reports · doi:10.1038/srep24038 · Cited by 122
Metadata
- Authors
- Bansode, A., & Urakawa, A.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-10-01
- Volume
- 4
- Issue
- 11
- Pages
- 3877-3880
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2331859255
- Cited by
- 184
- References
- 2
- FWCI
- 3.34
- Type
- journal article
- Language
- en
- Open access
- closed
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
