The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Formation and Growth of Humins via Aldol Addition and Condensation during Acid-Catalyzed Conversion of 5-Hydroxymethylfurfural
Abstract
The acid-catalyzed conversion of 5-hydroxymethylfurfural (HMF) produces levulinic and formic acids in equal amounts. Dark-colored solids, known as humins, are also formed in a parallel reaction. Aldol addition and condensation are proposed as important reactions in the acid-catalyzed growth of humins, adding HMF to 2,5-dioxo-6-hydroxy-hexanal. Consistent with this proposal, infrared (IR) spectra of humins formed from HMF indicate that the furan ring and hydroxymethyl group of HMF are present in the humins, but the carbonyl group is not. Similarly, if a mixture of HMF and benzaldehyde are processed, IR spectra of the humins indicate the additional presence of the aromatic ring from benzaldehyde but not its carbonyl group. The incorporation of the aromatic ring from benzaldehyde in the humins demonstrates the possibility of functionalizing humins to increase their value.
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Cites
Hydrothermal Conversion of Biomass: I, Glucose Conversion in Hot Compressed Water
Knežević, D., van Swaaij, W. P. M., & Kersten, S. R. A. (2009) · Industrial & Engineering Chemistry Research · doi:10.1021/ie801387v · Cited by 180
Cited by
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013) · Chemical Reviews · doi:10.1021/cr300182k · Cited by 2,886
Furfural: a renewable and versatile platform molecule for the synthesis of chemicals and fuels
Mariscal, R., Maireles-Torres, P., Ojeda, M., Sádaba, I., & López Granados, M. (2016) · Energy & Environmental Science · doi:10.1039/c5ee02666k · Cited by 1,642
van Zandvoort, I., Wang, Y., Rasrendra, C. B., van Eck, E. R. H., Bruijnincx, P. C. A., Heeres, H. J., & Weckhuysen, B. M. (2013) · ChemSusChem · doi:10.1002/cssc.201300332 · Cited by 624
From lignocellulosic biomass to levulinic acid: A review on acid-catalyzed hydrolysis
Kang, S., Fu, J., & Zhang, G. (2018) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2018.06.016 · Cited by 580
A review on the current status of various hydrothermal technologies on biomass feedstock
Kumar, M., Olajire Oyedun, A., & Kumar, A. (2018) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2017.05.270 · Cited by 534
Metadata
- Authors
- Patil, S. K. R., & Lund, C. R. F.
- Venue
- Energy & Fuels
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-09-09
- Volume
- 25
- Issue
- 10
- Pages
- 4745-4755
- ISSN
- 0887-0624 (ISSN-L)
- 1520-5029
- OpenAlex
- W2328984905
- Cited by
- 566
- References
- 1
- FWCI
- 16.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- Patil, S. K. R., & Lund, C. R. F. (2011). Formation and Growth of Humins via Aldol Addition and Condensation during Acid-Catalyzed Conversion of 5-Hydroxymethylfurfural. Energy & Fuels. https://doi.org/10.1021/ef2010157
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