The DOI matches its Crossref record; 39 of the 39 references it cites were found in a registry or an index.
Methane Adsorption on Shale under Simulated Geological Temperature and Pressure Conditions
Open accessAbstract
Shale gas is becoming an increasingly important energy resource. In this study, the adsorption of methane on a dry, organic-rich Alum shale sample was studied at pressures up to ∼14 MPa and temperatures in the range 300–473 K, which are relevant to gas storage under geological conditions. Maximum methane excess uptake was 0.176–0.042 mmol g –1 (125–30 scf t –1 ) for the temperature range of 300–473 K. The decrease in maximum methane surface excess with increasing temperature can be described with a linear model. An isosteric enthalpy of adsorption 19.2 ± 0.1 kJ mol –1 was determined at 0.025 mmol g –1 using the van’t Hoff equation. Supercritical adsorption was modeled using the modified Dubinin–Radushkevich and the Langmuir equations. The results are compared with absolute isotherms calculated from surface excess and the pore volumes obtained from subcritical gas adsorption (nitrogen (78 K), carbon dioxide (273 and 195 K), and CH 4 (112 K)). The subcritical adsorption and the surface excess results allow an upper limit to be put on the amount of gas that can be retained by adsorption during gas generation from petroleum source rocks.
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Cites
CRC Handbook of Chemistry and Physics
(2014) · doi:10.1201/b17118 · Cited by 57,706
The adsorption of gases on plane surfaces of glass, mica and platinum
Langmuir, I. (1918) · Journal of the American Chemical Society · doi:10.1021/ja02242a004 · Cited by 23,242
Adsorption surface area and porosity
Steele, W. A. (1983) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(83)90305-3 · Cited by 7,928
Span, R., & Wagner, W. (1996) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555991 · Cited by 5,049
Lemmon, E. W., Huber, M. L., & McLinden, M. O. (2007) · Cited by 4,201
Jarvie, D. M., Hill, R. J., Ruble, T. E., & Pollastro, R. M. (2007) · AAPG Bulletin · doi:10.1306/12190606068 · Cited by 3,146
Ross, D. J. K., & Marc Bustin, R. (2009) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2008.06.004 · Cited by 2,217
Adsorption Analysis: Equilibria and Kinetics: (With CD Containing Computer Matlab Programs)
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Sequestration of Carbon Dioxide in Coal with Enhanced Coalbed Methane RecoveryA Review
White, C. M., Smith, D. H., Jones, K. L., Goodman, A. L., Jikich, S. A., LaCount, R. B., DuBose, S. B., Ozdemir, E., Morsi, B. I., & Schroeder, K. T. (2005) · Energy & Fuels · doi:10.1021/ef040047w · Cited by 1,018
Cited by
Evolution of nanoporosity in organic-rich shales during thermal maturation
Chen, J., & Xiao, X. (2014) · Fuel · doi:10.1016/j.fuel.2014.03.058 · Cited by 401
Saha, D., Grappe, H. A., Chakraborty, A., & Orkoulas, G. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00745 · Cited by 316
Tian, H., Li, T., Zhang, T., & Xiao, X. (2016) · International Journal of Coal Geology · doi:10.1016/j.coal.2016.01.013 · Cited by 293
Metadata
- Authors
- Rexer, T. F. T., Benham, M. J., Aplin, A. C., & Thomas, K. M.
- Venue
- Energy & Fuels
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-05-28
- Volume
- 27
- Issue
- 6
- Pages
- 3099-3109
- ISSN
- 0887-0624 (ISSN-L)
- 1520-5029
- OpenAlex
- W2090582737
- Cited by
- 473
- References
- 39
- FWCI
- 26.49
- Type
- journal article
- Language
- en
- Open access
- green
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