The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Towards a Lignincellulosic Biorefinery: Direct One-Step Conversion of Lignin to Hydrogen-Enriched Biofuel
Abstract
This paper reports a novel liquefaction process that is capable of depolymerizing the natural biopolymer lignin into a liquid bio-oil with a very low oxygen content, suitable as a blending component to be combined with conventional fossil fuels for motor fuel applications. During the conversion, both depolymerization and removal of oxygen by formation of water occur in a single step. Formic acid serves as both the hydrogen donor and reaction medium in the pyrolysis/solvolysis process. Using an alcohol as cosolvent can improve the liquid yields and H/C ratios. Very little coke (5%) is produced. The liquids produced comprise two easily separable phases, where the lighter organic phase consists mainly of low molecular weight alkylphenols and C 8 −C 10 aliphatics. The process is developed to be combined with ethanol production from lignocellulosic carbohydrates in a biorefinery concept aimed at converting all fractions of the wood into renewably sourced liquid fuels.
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Citations
Cites
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review
Mohan, D., Pittman, C. U., & Steele, P. H. (2006) · Energy & Fuels · doi:10.1021/ef0502397 · Cited by 5,663
Ethanol for a Sustainable Energy Future
Goldemberg, J. (2007) · Science · doi:10.1126/science.1137013 · Cited by 1,423
Biorefineries: Current status, challenges, and future direction
Fernando, S., Adhikari, S., Chandrapal, C., & Murali, N. (2006) · Energy & Fuels · doi:10.1021/ef060097w · Cited by 709
The radical-induced decomposition of 2-methoxyphenol
Dorrestijn, E., & Mulder, P. (1999) · Journal of the Chemical Society, Perkin Transactions 2 · doi:10.1039/a809619h · Cited by 87
Cited by
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
Li, C., Zhao, X., Wang, A., Huber, G. W., & Zhang, T. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00155 · Cited by 2,951
Hydrothermal conversion of lignin: A review
Kang, S., Li, X., Fan, J., & Chang, J. (2013) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2013.07.013 · Cited by 552
Downstream processing of lignin derived feedstock into end products
Wong, S. S., Shu, R., Zhang, J., Liu, H., & Yan, N. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00134a · Cited by 528
Hanson, S. K., Wu, R., & Silks, L. A. “. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201107020 · Cited by 294
Brand, S., Susanti, R. F., Kim, S. K., Lee, H.-S., Kim, J., & Sang, B.-I. (2013) · Energy · doi:10.1016/j.energy.2013.06.049 · Cited by 211
Metadata
- Authors
- Kleinert, M., & Barth, T.
- Venue
- Energy & Fuels
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-02-27
- Volume
- 22
- Issue
- 2
- Pages
- 1371-1379
- ISSN
- 0887-0624 (ISSN-L)
- 1520-5029
- OpenAlex
- W1974331164
- Cited by
- 345
- References
- 4
- FWCI
- 13.22
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
