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Lignin pyrolysis products, lignans, and resin acids as specific tracers of plant classes in emissions from biomass combustion
Abstract
Biomass smoke aerosols contain thermally unaltered and partially altered biomarker compounds from major vegetation taxa. These compounds range from C_8 to C_(31) and include phytosterols, lignans, phenolic products from lignin, and diterpenoids from resins. Certain of the higher molecular weight biomarkers are vaporized from the parent plant material and subsequently condense unaltered into the particle phase. Other compounds undergo pyrolytic alteration and possibly dimerization. In both cases it is possible to assign many of these compounds to the plant taxa of the unburned fuel. The diterpenoids are good indicators for smoke from burning of gymnosperm wood. The relative distribution of the OH/OCH_3 substituent patterns on the phenolic products indicates the plant class of the biomass that was burned. Application of these relationships to the interpretation of ambient smoke aerosols may permit further evaluation of the sources that contribute to regional biomass burning.
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Cited by
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Oros, D. R., & Simoneit, B. R. T. (2000) · Fuel · doi:10.1016/s0016-2361(99)00153-2 · Cited by 373
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Self-citationInfluence of Interactions among Three Biomass Components on the Pyrolysis Behavior
Zhao, S., Liu, M., Zhao, L., & Zhu, L. (2018) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.8b00593 · Cited by 108
Dalluge, D. L., Kim, K. H., & Brown, R. C. (2017) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/j.jaap.2017.07.011 · Cited by 88
Temporal patterns in daily measurements of inorganic and organic speciated PM2.5 in Denver
Dutton, S. J., Rajagopalan, B., Vedal, S., & Hannigan, M. P. (2010) · Atmospheric Environment · doi:10.1016/j.atmosenv.2009.06.006 · Cited by 33
Metadata
- Authors
- Simoneit, B. R. T., Rogge, W. F., Mazurek, M. A., Standley, L. J., Hildemann, L. M., & Cass, G. R.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 1993-11-01
- Volume
- 27
- Issue
- 12
- Pages
- 2533-2541
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2025100133
- Cited by
- 443
- References
- 0
- FWCI
- 2.55
- Type
- journal article
- Language
- en
- Open access
- closed
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