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Cited by 406

The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.

Chromate adsorption on amorphous iron oxyhydroxide in the presence of major groundwater ions

Zachara, John M., Girvin, Donald C., Schmidt, Ronald L., Resch, C. Thomas.·1987·Environmental Science & Technology

Abstract

Chromate adsorption on amorphous iron oxyhydroxide was investigated in dilute iron suspensions as a single solute and in solutions of increasing complexity containing CO2 (g), SO42-(aq), H4Si04(aq), and cations [K+, Mg2+, Ca2+(aq)]. In paired-solute systems (e.g., CrO42- =H2CO3*), anionic cosolutes markedly reduce CrO42- adsorption through a combination of competitive and electrostatic effects, but cations exert no appreciable influence. Additionally, H4Si04 exhibits a strong time-dependent effect: CrO42- adsorption is greatly decreased with increasing H4SiO4 contact time. In multiple-ion mixtures, each anion added to the mixture decreases CrO42- adsorption further. Adsorption constants for the individual reactive solutes were used in the triple-layer model. The model calculations are in good agreement with the CrO42- adsorption data for paired- and multiple-solute systems. However, the model calculations underestimate CrO42- adsorption when surface site saturation is appr6ached. Questions remain regarding the surface interactions of both CO2(aq) and H4Si04. The results have major implications for the adsorption behavior of CrO42- and other oxyanions in subsurface waters.

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Metadata

Authors
Zachara, J. M., Girvin, D. C., Schmidt, R. L., & Resch, C. T.
Venue
Environmental Science & Technology
Published
1987-06
Volume
21
Issue
6
Pages
589-594
ISSN
  • 0013-936X (ISSN-L)
  • 1520-5851
OpenAlex
W2042552267
Cited by
406
References
6
FWCI
4.00
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Chromate adsorption on amorphous iron oxyhydroxide in the presence of major groundwater ions. https://app.cochat.ai/papers/10.1021/es00160a010
The paper
Zachara, J. M., Girvin, D. C., Schmidt, R. L., & Resch, C. T. (1987). Chromate adsorption on amorphous iron oxyhydroxide in the presence of major groundwater ions. Environmental Science & Technology. https://doi.org/10.1021/es00160a010

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.