Surface reactions of chromium in soils and waters

Fendorf, Scott E.

doi:10.1016/0016-7061(94)00062-f

Cited by 680Chromium effects and bioremediationHeavy metals in environmentEnvironmental and Analytical Chemistry Studies

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Surface reactions of chromium in soils and waters

Fendorf, Scott E.·1995·Geoderma

DOI 10.1016/0016-7061(94)00062-f

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Organic material, sulfides, and ferrous species appear to be the dominant reductants.
“Organic material, sulfides, and ferrous species appear to be the dominant reductants.”
From Chemical Processes Affecting the Mobility of Heavy Metals and Metalloids in Soil Environments (2016) · cites this paper as [30]
Very stable Cr(III)-organic complexes form when Cr(VI) is reduced by soil organic matter.
“Very stable Cr(III)-organic complexes form when Cr(VI) is reduced by soil organic matter [28, 30].”
From Chemical Processes Affecting the Mobility of Heavy Metals and Metalloids in Soil Environments (2016) · cites this paper as [30]
Dissolved Cr dispersal would be limited upon delivery to the oceans due to low solubility of Cr(III) at marine pH, rapid reduction of Cr(VI) by aqueous Fe(II), and near-instantaneous coprecipitation of Cr(III) with Fe(III)-oxyhydroxide.
“Considering the low solubility of Cr(III) at marine pH levels, the rapid reduction of Cr(VI) by aqueous Fe(II), and near-instantaneous coprecipitation of Cr(III) with Fe(III)-oxyhydroxide (e.g., Fendorf, 1995), dissolved Cr dispersal would be limited upon delivery to the oceans.”
From Iron formations: A global record of Neoarchaean to Palaeoproterozoic environmental history (2017) · cites this paper as Fendorf, 1995
In modern soils, Mn-oxide phases catalyze the oxidation of Cr(III) to Cr(VI).
“the oxidation of Cr(III) to Cr(VI) in modern soils is catalyzed by interaction between Cr(III) and Mn-oxide phases (MnO2)”
From The chromium isotope composition of reducing and oxic marine sediments (2016) · cites this paper as Fendorf, 1995
Cr(III) is less mobile in soil, and conversion of Cr(VI) to a trivalent oxide or co-precipitation with Fe hydrous oxide reduces Cr mobility and bioavailability in soil.
“Because Cr(III) is less mobile in soil, conversion of Cr(VI) to a trivalent oxide or co-precipitation with Fe hydrous oxide reduces Cr mobility and bioavailability in soil (Fendorf, 1995).”
From Soil amendments for immobilization of potentially toxic elements in contaminated soils: A critical review (2020) · cites this paper as Fendorf, 1995

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Sohn, M. (1988) · Organic Geochemistry · doi:10.1016/0146-6380(88)90267-7 · Cited by 1,072
Aquatic Surface Chemistry
Olis, A. C. (1988) · Soil Science · doi:10.1097/00010694-198809000-00018 · Cited by 796
Chromium(III) hydrolysis constants and solubility of chromium(III) hydroxide
Rai, D., Sass, B. M., & Moore, D. A. (1987) · Inorganic Chemistry · doi:10.1021/ic00250a002 · Cited by 698
Chromate removal from aqueous wastes by reduction with ferrous ion
Eary, L. E., & Raics, P. (1988) · Environmental Science & Technology · doi:10.1021/es00173a018 · Cited by 608
Behavior of Chromium in Soils: III. Oxidation
Bartlett, R., & James, B. (1979) · Journal of Environmental Quality · doi:10.2134/jeq1979.00472425000800010008x · Cited by 570
Chromium in the natural and human environments
Nriagu, J. O., & Nieboer, E. (1988) · Wiley eBooks · Cited by 544
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Eary, L. E., & Rai, D. (1987) · Environmental Science & Technology · doi:10.1021/es00165a005 · Cited by 496
Chromate adsorption on amorphous iron oxyhydroxide in the presence of major groundwater ions
Zachara, J. M., Girvin, D. C., Schmidt, R. L., et al. (1987) · Environmental Science & Technology · doi:10.1021/es00160a010 · Cited by 408
Chromium reduction in Pseudomonas putida
Ishibashi, Y., Cervantes, C., & Silver, S. D. (1990) · Applied and Environmental Microbiology · doi:10.1128/aem.56.7.2268-2270.1990 · Cited by 393
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Fendorf, S. E., & Zasoski, R. J. (1992) · Environmental Science & Technology · doi:10.1021/es00025a006 · Cited by 389
Self-citation
Solubility of amorphous chromium(III)-iron(III) hydroxide solid solutions
Sass, B. M., & Rai, D. (1987) · Inorganic Chemistry · doi:10.1021/ic00261a013 · Cited by 349
X-ray absorption spectroscopic study of the sorption of Cr(III) at the oxide-water interface
Charlet, L., & Manceau, A. (1992) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(92)90182-l · Cited by 333
Behavior of Chromium in Soils: II. Hexavalent Forms
Bartlett, R. J., & Kimble, J. M. (1976) · Journal of Environmental Quality · doi:10.2134/jeq1976.00472425000500040010x · Cited by 277
X-ray absorption spectroscopic study of the sorption of Cr(III) at the oxide-water interface
Manceau, A., & Charlet, L. (1992) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(92)90181-k · Cited by 268
Behavior of Chromium in Soils: VII. Adsorption and Reduction of Hexavalent Forms
James, B. R., & Bartlett, R. J. (1983) · Journal of Environmental Quality · doi:10.2134/jeq1983.00472425001200020005x · Cited by 257
Chromium in the natural and human environments
Bryce‐Smith, D. (1989) · Endeavour · doi:10.1016/0160-9327(89)90073-2 · Cited by 243
Adsorption of Chromate by Subsurface Soil Horizons
Zachara, J. M., Ainsworth, C. C., Cowan, C. E., & Resch, C. T. (1989) · Soil Science Society of America Journal · doi:10.2136/sssaj1989.03615995005300020018x · Cited by 230
Electron Transfer Reactions of Complex Ions in Solution
(1970) · Elsevier eBooks · doi:10.1016/b978-0-12-683850-3.x5001-8 · Cited by 220
Early stages of the hydrolysis of chromium(III) in aqueous solution. 1. Characterization of a tetrameric species
Stuenzi, H., & Marty, W. (1983) · Inorganic Chemistry · doi:10.1021/ic00157a012 · Cited by 212
Kinetics of chromate reduction by ferrous ions derived from hematite and biotite at 25 degrees C
Eary, L. E., & Raics, P. (1989) · American Journal of Science · doi:10.2475/ajs.289.2.180 · Cited by 207
Behavior of Chromium in Soils. VI. Interactions Between Oxidation‐Reduction and Organic Complexation
James, B. R., & Bartlett, R. J. (1983) · Journal of Environmental Quality · doi:10.2134/jeq1983.00472425001200020004x · Cited by 206
Behavior of Chromium in Soils: I. Trivalent Forms
Bartlett, R. J., & Kimble, J. M. (1976) · Journal of Environmental Quality · doi:10.2134/jeq1976.00472425000500040009x · Cited by 199
Behavior of Chromium in Soils: V. Fate of Organically Complexed Cr(III) Added to Soil
James, B. R., & Bartlett, R. J. (1983) · Journal of Environmental Quality · doi:10.2134/jeq1983.00472425001200020003x · Cited by 192
Effects of Chromium on Growth and Mineral Nutrition of Soybeans
Turner, M. A., & Rust, R. H. (1971) · Soil Science Society of America Journal · doi:10.2136/sssaj1971.03615995003500050035x · Cited by 169
Chromate Reduction by Subsurface Soils under Acidic Conditions
Eary, L. E., & Rai, D. (1991) · Soil Science Society of America Journal · doi:10.2136/sssaj1991.03615995005500030007x · Cited by 160
Mechanisms of chromium(III) sorption on silica. 1. Chromium(III) surface structure derived by extended x-ray absorption fine structure spectroscopy
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Self-citation
Chromium Redox Chemistry in a Lower Mississippi Valley Bottomland Hardwood Wetland
Masscheleyn, P. H., Pardue, J. H., DeLaune, R. D., et al. (1992) · Environmental Science & Technology · doi:10.1021/es50002a611 · Cited by 149
Mobility and bioavailability of chromium in soils
Bartlett, R. J., & James, B. R. (1988) · Advances in environmental science and technology · Cited by 149
Kinetics of chromium transformations in the environment
Salem, F. Y., Parkerton, T. F., Lewis, R. V., et al. (1989) · The Science of The Total Environment · doi:10.1016/0048-9697(89)90190-3 · Cited by 145
Batch experiments characterizing the reduction of chromium(VI) using suboxic material from a mildly reducing sand and gravel aquifer
Anderson, L. D., Kent, D. B., & Davis, J. A. (1994) · Environmental Science & Technology · doi:10.1021/es00050a025 · Cited by 140
Chemical speciation of chromium in sea water
Nakayama, E., Kuwamoto, T., Tsurubo, S., Tokoro, H., & Fujinaga, T. (1981) · Analytica Chimica Acta · doi:10.1016/s0003-2670(01)93006-5 · Cited by 128
Inhibitory mechanisms of Cr(III) oxidation by δ-MnO2
Fendorf, S. E., Fendorf, M., Sparks, D. L., & Gronsky, R. (1992) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(92)90296-x · Cited by 125
Self-citation
Effect of pH on adsorption of chromium from landfill‐leachate by clay minerals
Griffin, R. A., Au, A. K., & Frost, R. R. (1977) · Journal of Environmental Science and Health Part A Environmental Science and Engineering · doi:10.1080/10934527709374769 · Cited by 115
Chemical speciation of chromium in sea water
Nakayama, E., Kuwamoto, T., Tsurubo, S., & Fujinaga, T. (1981) · Analytica Chimica Acta · doi:10.1016/s0003-2670(01)93020-x · Cited by 113
The oxidation of chromium(III) to chromium(VI) on the surface of manganite (γ-MnOOH)
Johnson, C. A., & Xyla, A. G. (1991) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(91)90451-a · Cited by 110
Chromate Adsorption on Goethite: Effects of Aluminum Substitution
Ainsworth, C. C., Girvin, D. C., Zachara, J. M., et al. (1989) · Soil Science Society of America Journal · doi:10.2136/sssaj1989.03615995005300020017x · Cited by 97
ADSORPTION FROM AQUEOUS SOLUTION
(1970) · Analytical Chemistry · doi:10.1021/ac60285a824 · Cited by 87
Adsorption kinetics of vanadyl (IV) and chromium (III) to aluminum oxide: Evidence for a two-step mechanism
Wehrli, B., Ibrić, S., & Stumm, W. (1990) · Colloids and Surfaces · doi:10.1016/0166-6622(90)80133-o · Cited by 71
Redox reactions involving chromium, plutonium, and manganese in soils
Amacher, M. C., & Baker, D. E. (1979) · doi:10.2172/5060685 · Cited by 62
Effects of Strong Binding of Anionic Adsorbates on Adsorption of Trace Metals on Amorphous Iron Oxyhydroxide
Benjamin, M. M., & Bloom, N. S. (1981) · Springer eBooks · doi:10.1007/978-1-4613-3264-0_3 · Cited by 61
Adsorption from aqueous solution
Adamson, A. W. (1969) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(69)90069-1 · Cited by 56
Competing Metal Ion Influences on Chromium(III) Oxidation by Birnessite
Fendorf, S. E., Zasoski, R. J., & Burau, R. G. (1993) · Soil Science Society of America Journal · doi:10.2136/sssaj1993.03615995005700060019x · Cited by 54
Self-citation
Interaction of monomeric and polymeric species of metal ions with clay surfaces. III. Aluminium(III) and chromium(III)
Rengasamy, P., & Oades, J. (1978) · Soil Research · doi:10.1071/sr9780053 · Cited by 50
Scanning tunneling microscopy of Cr(III) chemisorbed on α-Fe2O3 (001) surfaces from aqueous solution: Direct observation of surface mobility and clustering
Eggleston, C. M., & Stumm, W. (1993) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(93)90203-9 · Cited by 46
Hydroxy-Chromium Smectite
Volzone, C., Cesio, A. M., Sánchez, R. M. T., et al. (1993) · Clays and Clay Minerals · doi:10.1346/ccmn.1993.0410608 · Cited by 30
Thermodynamic properties and environmental chemistry of chromium
Schmidt, R. L. (1984) · doi:10.2172/6675931 · Cited by 27
EXAFS studies of pillared clay catalysts
Corker, J. M., Evans, J., & Rummey, J. M. (1991) · Materials Chemistry and Physics · doi:10.1016/0254-0584(91)90016-n · Cited by 21
Kinetics of the oxidation of chromium(III) ions by trimanganese tetroxide and by manganese(III) oxide
Rophael, M. W., & Boulis, S. N. (1982) · Surface Technology · doi:10.1016/0376-4583(82)90115-7 · Cited by 17

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Authors: Fendorf, S. E.
Affiliations: University of Idaho (US)
Corresponding author: Fendorf, Scott E.
ORCID: Fendorf, Scott E.
Venue: Geoderma
Publisher: Elsevier BV
Published: 1995-06
Volume: 67
Issue: 1-2
Pages: 55-71
ISSN: 0016-7061 (ISSN-L)
DOI: 10.1016/0016-7061(94)00062-f
OpenAlex: W1983714620
Cited by: 680
References: 48
Citations by year: 2026: 20 · 2025: 20 · 2024: 19 · 2023: 40 · 2022: 38 · 2021: 32 · 2020: 42 · 2019: 35 · 2018: 34 · 2017: 32 · 2016: 39 · 2015: 42 · 2014: 28 · 2013: 36 · 2012: 34
FWCI: 3.88
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
Locations: Geoderma (publishedVersion)
Topics: Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Chromium effects and bioremediation
Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
Keywords: chromium, trivalent chromium, hexavalent chromium, redox reactions, solid-water interface, adsorption, goethite, manganese oxide, iron(II) reduction, bioavailability, soil contamination, heavy metal mobility, sorption

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