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Reactivity of Fe(II)-Bearing Minerals toward Reductive Transformation of Organic Contaminants

Elsner, Martin, Schwarzenbach, René P., Haderlein, Stefan B.·2004·Environmental Science & Technology
DOI 10.1021/es0345569
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Abstract

Fe(II) present at surfaces of iron-containing minerals can play a significant role in the overall attenuation of reducible contaminants in the subsurface. As the chemical environment, i.e., the type and arrangement of ligands, strongly affects the redox potential of Fe(II), the presence of various mineral sorbents is expected to modulate the reactivity of surficial Fe(II)-species in aqueous systems. In a comparative study we evaluated the reactivity of ferrous iron in aqueous suspensions of siderite (FeCO3), nontronite (ferruginous smectite SWa-1), hematite (alpha-Fe2O3), lepidocrocite (gamma-FeOOH), goethite (alpha-FeOOH), magnetite (Fe3O4), sulfate green rust (Fe(II)4Fe(III)2(OH)12SO4 x 4H2O), pyrite (FeS2), and mackinawite (FeS) under similar conditions (pH 7.2, 25 m2 mineral/L, 1 mM Fe(II)aq, O2 (aq) < 0.1 g/L). Surface-area-normalized pseudo first-order rate constants are reported for the reduction of hexachloroethane and 4-chloronitrobenzene representing two classes of environmentally relevant transformation reactions of pollutants, i.e., dehalogenation and nitroaryl reduction. The reactivities of the different Fe(II) mineral systems varied greatly and systematically both within and between the two data sets obtained with the two probe compounds. As a general trend, surface-area-normalized reaction rates increased in the order Fe(II) + siderite < Fe(II) + iron oxides < Fe(II) + iron sulfides. 4-Chloronitrobenzene was transformed by mineral-bound Fe(II) much more rapidly…

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Metadata

Authors
Elsner, M., Schwarzenbach, R. P., & Haderlein, S. B.
Affiliations
Swiss Federal Institute for Environmental Science and Technology (EAWAG) and Swiss Federal Institute of Technology Zurich (ETHZ), Ueberlandstrasse 133, CH-8600 Duebendorf, Switzerland
Venue
Environmental Science & Technology
Publisher
American Chemical Society (ACS)
Published
2003-12-23
Volume
38
Issue
3
Pages
799-807
ISSN
  • 0013-936X
  • 1520-5851
DOI
10.1021/es0345569
Cited by
343
References
2
Language
en

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