The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
The Origin of Naturally Occurring Perchlorate: The Role of Atmospheric Processes
Abstract
Perchlorate, an iodide uptake inhibitor, is increasingly being detected in new places and new matrices. Perchlorate contamination has been attributed largelyto the manufacture and use of ammonium perchlorate (the oxidizer in solid fuel rockets) and/or the earlier use of Chilean nitrate as fertilizer (approximately 0.1% perchlorate). However, there are regions such as the southern high plains (Texas Panhandle) where there is no clear historical or current evidence of the extensive presence of rocket fuel or Chilean fertilizer sources. The occurrence of easily measurable concentrations of perchlorate in such places is difficult to understand. In the southern high plains groundwater, perchlorate is better correlated with iodate, known to be of atmospheric origin, compared to any other species. We show that perchlorate is readily formed by a variety of simulated atmospheric processes. For example, it is formed from chloride aerosol by electrical discharge and by exposing aqueous chloride to high concentrations of ozone. We report that perchlorate is present in many rain and snow samples. This strongly suggests that some perchlorate is formed in the atmosphere and a natural perchlorate background of atmospheric origin should exist.
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African droughts and dust transport to the caribbean: climate change implications
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Inactivating Mutations in the Gene for Thyroid Oxidase 2 (THOX2) and Congenital Hypothyroidism
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A Reservoir of Nitrate Beneath Desert Soils
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Formation of Molecular Chlorine from the Photolysis of Ozone and Aqueous Sea-Salt Particles
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Cited by
Blount, B. C., Pirkle, J. L., Osterloh, J. D., Valentin-Blasini, L., & Caldwell, K. L. (2006) · Environmental Health Perspectives · doi:10.1289/ehp.9466 · Cited by 344
Atmospheric origins of perchlorate on Mars and in the Atacama
Catling, D. C., Claire, M. W., Zahnle, K. J., Quinn, R. C., Clark, B. C., Hecht, M. H., & Kounaves, S. (2010) · Journal of Geophysical Research: Planets · doi:10.1029/2009je003425 · Cited by 304
Water Analysis: Emerging Contaminants and Current Issues
Richardson, S. D. (2007) · Analytical Chemistry · doi:10.1021/ac070719q · Cited by 233
The Origins of Perchlorate in the Martian Soil
Carrier, B. L., & Kounaves, S. P. (2015) · Geophysical Research Letters · doi:10.1002/2015gl064290 · Cited by 160
Perchlorate, iodine and the thyroid
Leung, A. M., Pearce, E. N., & Braverman, L. E. (2010) · Best Practice & Research Clinical Endocrinology & Metabolism · doi:10.1016/j.beem.2009.08.009 · Cited by 152
Metadata
- Authors
- Dasgupta, P. K., Martinelango, P. K., Jackson, W. A., Anderson, T. A., Tian, K., Tock, R. W., & Rajagopalan, S.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-01-29
- Volume
- 39
- Issue
- 6
- Pages
- 1569-1575
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2045284443
- Cited by
- 438
- References
- 29
- FWCI
- 23.79
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dasgupta, P. K., Martinelango, P. K., Jackson, W. A., Anderson, T. A., Tian, K., Tock, R. W., & Rajagopalan, S. (2005). The Origin of Naturally Occurring Perchlorate: The Role of Atmospheric Processes. Environmental Science & Technology. https://doi.org/10.1021/es048612x
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