The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
Kinetics of the Oxidation of Phenols and Phenolic Endocrine Disruptors during Water Treatment with Ferrate (Fe(VI))
Open accessAbstract
The ability of ferrate (Fe(VI)) to oxidize phenolic endocrine-disrupting chemicals (EDCs) and phenols during water treatment was examined by determining the apparent second-order rate constants (k(app0) for the reaction of Fe(VI) with selected environmentally relevant phenolic EDCs (17alpha-ethinylestradiol, beta-estradiol, and bisphenol A) and 10 substituted phenols at pH values ranging from 6 to 11. The three selected groups of EDCs showed appreciable reactivity with Fe(VI) (kapp at pH 7 ranged from 6.4 x 102 to 7.7 x 10(2) M(-1) s(-1)). The k(app) for the substituted phenols studied at pH 7 ranged from 6.6 to 3.6 x 10(3) M(-1) s(-1), indicating that many other potential phenolic EDCs can be oxidized by Fe(VI) during water treatment. The Hammett-type correlations were determined for the reaction between HFeO4- and the undissociated (log(k) = 2.24-2.27sigma+) and dissociated phenol (log(k) = 4.33-3.60sigma+). A comparison of the Hammett correlation obtained for the reaction between HFeO4- and dissociated phenol with those obtained from other drinking water oxidants revealed that HFeO4- is a relatively mild oxidant of phenolic compounds. The effectiveness of Fe(VI) for the oxidative removal of phenolic EDCs was also confirmed in both natural water and wastewater.
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Cites
A survey of Hammett substituent constants and resonance and field parameters
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Self-citationPotassium ferrate(VI): an environmentally friendly oxidant
Sharma, V. K. (2002) · Advances in Environmental Research · doi:10.1016/s1093-0191(01)00119-8 · Cited by 493
Chlorination of Phenols: Kinetics and Formation of Chloroform
Gallard, H., & von Gunten, U. (2002) · Environmental Science & Technology · doi:10.1021/es010076a · Cited by 412
Self-citationFormation of Iodo-Trihalomethanes during Disinfection and Oxidation of Iodide-Containing Waters
Bichsel, Y., & von Gunten, U. (2000) · Environmental Science & Technology · doi:10.1021/es9914590 · Cited by 406
Self-citationOxidation of pharmaceuticals during water treatment with chlorine dioxide
Huber, M. M., Korhonen, S., Ternes, T. A., & von Gunten, U. (2005) · Water Research · doi:10.1016/j.watres.2005.05.040 · Cited by 322
Self-citationHuber, M. M., Ternes, T. A., & von Gunten, U. (2004) · Environmental Science & Technology · doi:10.1021/es035205x · Cited by 267
Self-citationKolpin, D. W., Furlong, E. T., Meyer, M. T., Thurman, E. M., Zaugg, S. D., Barber, L. B., & Buxton, H. T. (2002) · Environmental Science & Technology · doi:10.1021/es020136s · Cited by 175
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Feng, L., van Hullebusch, E. D., Rodrigo, M. A., Esposito, G., & Oturan, M. A. (2013) · Chemical Engineering Journal · doi:10.1016/j.cej.2013.05.061 · Cited by 543
Jiang, J.-Q., Zhou, Z., & Sharma, V. K. (2013) · Microchemical Journal · doi:10.1016/j.microc.2013.04.014 · Cited by 401
Zhou, Y., Jiang, J., Gao, Y., Pang, S.-Y., Yang, Y., Ma, J., Gu, J., Li, J., Wang, Z., Wang, L.-H., et al. (2017) · Water Research · doi:10.1016/j.watres.2017.08.049 · Cited by 346
Metadata
- Authors
- Lee, Y., Yoon, J., & von Gunten, U.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-10-18
- Volume
- 39
- Issue
- 22
- Pages
- 8978-8984
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W1984182687
- Cited by
- 292
- References
- 22
- FWCI
- 8.69
- Type
- journal article
- Language
- en
- Open access
- green
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- Lee, Y., Yoon, J., & von Gunten, U. (2005). Kinetics of the Oxidation of Phenols and Phenolic Endocrine Disruptors during Water Treatment with Ferrate (Fe(VI)). Environmental Science & Technology. https://doi.org/10.1021/es051198w
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