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Indoor Secondary Pollutants from Household Product Emissions in the Presence of Ozone: A Bench-Scale Chamber Study
Open accessAbstract
Ozone-driven chemistry is a source of indoor secondary pollutants of potential health concern. This study investigates secondary air pollutants formed from reactions between constituents of household products and ozone. Gas-phase product emissions were introduced along with ozone at constant rates into a 198-L Teflon-lined reaction chamber. Gas-phase concentrations of reactive terpenoids and oxidation products were measured. Formaldehyde was a predominant oxidation byproduct for the three studied products, with yields for most conditions of 20-30% with respect to ozone consumed. Acetaldehyde, acetone, glycolaldehyde, formic acid, and acetic acid were each also detected for two or three of the products. Immediately upon mixing of reactants, a scanning mobility particle sizer detected particle nucleation events that were followed by a significant degree of secondary particle growth. The production of secondary gaseous pollutants and particles depended primarily on the ozone level and was influenced by other parameters such as the air-exchange rate. Hydroxyl radical concentrations in the range 0.04-200 x 10(5) molecules cm(-3) were determined by an indirect method. OH concentrations were observed to vary strongly with residual ozone level in the chamber, which was in the range 1-25 ppb, as is consistent with expectations from a simplified kinetic model. In a separate chamber study, we exposed the dry residue of two products to ozone and observed the formation of gas-phase and particle-phase secondary oxidation products.
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Cited by
Formaldehyde in the Indoor Environment
Salthammer, T., Mentese, S., & Marutzky, R. (2010) · Chemical Reviews · doi:10.1021/cr800399g · Cited by 1,808
Volatile chemical products emerging as largest petrochemical source of urban organic emissions
McDonald, B. C., de Gouw, J. A., Gilman, J. B., Jathar, S. H., Akherati, A., Cappa, C. D., Jimenez, J. L., Lee-Taylor, J., Hayes, P. L., McKeen, S. A., et al. (2018) · Science · doi:10.1126/science.aaq0524 · Cited by 1,373
Wisthaler, A., & Weschler, C. J. (2010) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0904498106 · Cited by 444
Self-citationIndoor air pollutants in office environments: Assessment of comfort, health, and performance
Wolkoff, P. (2013) · International Journal of Hygiene and Environmental Health · doi:10.1016/j.ijheh.2012.08.001 · Cited by 342
Indoor secondary pollutants from cleaning product and air freshener use in the presence of ozone
Singer, B. C., Coleman, B. K., Destaillats, H., Hodgson, A. T., Lunden, M. M., Weschler, C. J., & Nazaroff, W. W. (2006) · Atmospheric Environment · doi:10.1016/j.atmosenv.2006.06.005 · Cited by 330
Self-citation
Metadata
- Authors
- Destaillats, H., Lunden, M. M., Singer, B. C., Coleman, B. K., Hodgson, A. T., Weschler, C. J., & Nazaroff, W. W.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-06-09
- Volume
- 40
- Issue
- 14
- Pages
- 4421-4428
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W1988395421
- Cited by
- 284
- References
- 1
- FWCI
- 11.68
- Type
- journal article
- Language
- en
- Open access
- green
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- Destaillats, H., Lunden, M. M., Singer, B. C., Coleman, B. K., Hodgson, A. T., Weschler, C. J., & Nazaroff, W. W. (2006). Indoor Secondary Pollutants from Household Product Emissions in the Presence of Ozone: A Bench-Scale Chamber Study. Environmental Science & Technology. https://doi.org/10.1021/es052198z
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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