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Cited by 284

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Indoor Secondary Pollutants from Household Product Emissions in the Presence of Ozone: A Bench-Scale Chamber Study

Open access
Destaillats, Hugo, Lunden, Melissa M., Singer, Brett C., Coleman, Beverly K., Hodgson, Alfred T., Weschler, Charles J., Nazaroff, William W.·2006·Environmental Science & Technology

Abstract

Ozone-driven chemistry is a source of indoor secondary pollutants of potential health concern. This study investigates secondary air pollutants formed from reactions between constituents of household products and ozone. Gas-phase product emissions were introduced along with ozone at constant rates into a 198-L Teflon-lined reaction chamber. Gas-phase concentrations of reactive terpenoids and oxidation products were measured. Formaldehyde was a predominant oxidation byproduct for the three studied products, with yields for most conditions of 20-30% with respect to ozone consumed. Acetaldehyde, acetone, glycolaldehyde, formic acid, and acetic acid were each also detected for two or three of the products. Immediately upon mixing of reactants, a scanning mobility particle sizer detected particle nucleation events that were followed by a significant degree of secondary particle growth. The production of secondary gaseous pollutants and particles depended primarily on the ozone level and was influenced by other parameters such as the air-exchange rate. Hydroxyl radical concentrations in the range 0.04-200 x 10(5) molecules cm(-3) were determined by an indirect method. OH concentrations were observed to vary strongly with residual ozone level in the chamber, which was in the range 1-25 ppb, as is consistent with expectations from a simplified kinetic model. In a separate chamber study, we exposed the dry residue of two products to ozone and observed the formation of gas-phase and particle-phase secondary oxidation products.

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Metadata

Authors
Destaillats, H., Lunden, M. M., Singer, B. C., Coleman, B. K., Hodgson, A. T., Weschler, C. J., & Nazaroff, W. W.
Venue
Environmental Science & Technology
Published
2006-06-09
Volume
40
Issue
14
Pages
4421-4428
ISSN
  • 0013-936X (ISSN-L)
  • 1520-5851
OpenAlex
W1988395421
Cited by
284
References
1
FWCI
11.68
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Indoor Secondary Pollutants from Household Product Emissions in the Presence of Ozone: A Bench-Scale Chamber Study. https://app.cochat.ai/papers/10.1021/es052198z
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Destaillats, H., Lunden, M. M., Singer, B. C., Coleman, B. K., Hodgson, A. T., Weschler, C. J., & Nazaroff, W. W. (2006). Indoor Secondary Pollutants from Household Product Emissions in the Presence of Ozone: A Bench-Scale Chamber Study. Environmental Science & Technology. https://doi.org/10.1021/es052198z

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