Volatile chemical products emerging as largest petrochemical source of urban organic emissions
Open accessAbstract
A gap in emission inventories of urban volatile organic compound (VOC) sources, which contribute to regional ozone and aerosol burdens, has increased as transportation emissions in the United States and Europe have declined rapidly. A detailed mass balance demonstrates that the use of volatile chemical products (VCPs)-including pesticides, coatings, printing inks, adhesives, cleaning agents, and personal care products-now constitutes half of fossil fuel VOC emissions in industrialized cities. The high fraction of VCP emissions is consistent with observed urban outdoor and indoor air measurements. We show that human exposure to carbonaceous aerosols of fossil origin is transitioning away from transportation-related sources and toward VCPs. Existing U.S. regulations on VCPs emphasize mitigating ozone and air toxics, but they currently exempt many chemicals that lead to secondary organic aerosols.
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The current WHO Air Quality Guidelines for ambient ozone is 100 μg/m3 (~50 ppb) measured as 8-h maximum moving average within a day.
“The current WHO Air Quality Guidelines for ambient (outdoor) ozone is 100 μg/m3 (~50 ppb) measured as 8-h maximum moving average within a day1.”
From Ozone pollution: A Major health hazard worldwide (2019) · cites this paper as [1]
Ozone can cause coughing and sore or scratchy throat.
“Ozone can cause coughing and sore or scratchy throat.”
From Ozone pollution: A Major health hazard worldwide (2019) · cites this paper as [1]
Ozone exposure makes the lungs more susceptible to infection.
“Ozone exposure makes the lungs more susceptible to infection.”
From Ozone pollution: A Major health hazard worldwide (2019) · cites this paper as [1]
Ozone continues to damage the lungs even when the symptoms have disappeared.
“Ozone continues to damage the lungs even when the symptoms have disappeared.”
From Ozone pollution: A Major health hazard worldwide (2019) · cites this paper as [1]
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Ozone pollution: A Major health hazard worldwide
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Tropospheric Ozone Assessment Report
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- Authors
- McDonald, B. C., de Gouw, J. A., Gilman, J. B., Jathar, S. H., Akherati, A., Cappa, C. D., Jimenez, J. L., Lee-Taylor, J., Hayes, P. L., McKeen, S. A., Cui, Y. Y., Kim, S.-W., Gentner, D. R., Isaacman-VanWertz, G., Goldstein, A. H., Harley, R. A., Frost, G. J., Roberts, J. M., Ryerson, T. B., & Trainer, M.
- Affiliations
- Cooperative Institute for Research in Environmental Sciences (US)
- Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA.
- NOAA Earth System Research Laboratory (US)
- Colorado State University (US)
- University of California, Davis (US)
- Université de Montréal (CA)
- Yale University (US)
- Virginia Tech (US)
- University of California, Berkeley (US)
- Corresponding author
- McDonald, Brian C.
- ORCID
- McDonald, Brian C.
- de Gouw, Joost A.
- Gilman, Jessica B.
- Jathar, Shantanu H.
- Akherati, Ali
- Cappa, Christopher D.
- Jimenez, Jose L.
- Lee-Taylor, Julia
- Hayes, Patrick L.
- McKeen, Stuart A.
- Cui, Yu Yan
- Kim, Si-Wan
- Gentner, Drew R.
- Isaacman-VanWertz, Gabriel
- Goldstein, Allen H.
- Harley, Robert A.
- Frost, Gregory J.
- Roberts, James M.
- Ryerson, Thomas B.
- Trainer, Michael
- Venue
- Science
- Published
- 2018-02-16
- Volume
- 359
- Issue
- 6377
- Pages
- 760-764
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2785649357
- Cited by
- 1,373
- References
- 126
- Citations by year
- 2026: 150 · 2025: 160 · 2024: 201 · 2023: 183 · 2022: 201 · 2021: 169 · 2020: 160 · 2019: 102 · 2018: 46 · 2012: 1
- FWCI
- 57.99
- Type
- journal article
- Language
- en
- Open access
- Licence
- public-domain
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- NOAA Institutional Repository (submittedVersion, public-domain)
- Funders
- National Science Foundation (AGS-1360834, AGS-1151062)
- National Oceanic and Atmospheric Administration (NA17OAR4310003)
- Alfred P. Sloan Foundation (2016-7173, G-2016-7050)
- Natural Sciences and Engineering Research Council of Canada (RGPIN/05002-2014)
- Fonds de Recherche du Québec Nature et Technologies (2016-PR-192364)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
- Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Toxic Organic Pollutants Impact
- Physical Sciences › Environmental Science › Global and Planetary Change › Atmospheric and Environmental Gas Dynamics
- Keywords
- volatile chemical products, VOC emission inventory, secondary organic aerosol, ozone, pesticides, surface coating, printing inks, adhesives, cleaning agents, personal care products, mass balance, air pollution regulation, indoor air quality
- MeSH terms
- Air Pollutants, Dioctyl Sulfosuccinic Acid, Environmental Exposure, Humans, Hydrocarbons, United States, Volatile Organic Compounds
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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