The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
UV Degradation Kinetics and Modeling of Pharmaceutical Compounds in Laboratory Grade and Surface Water via Direct and Indirect Photolysis at 254 nm
Abstract
Direct and indirect photolysis of pharmaceutically active compounds (PhACs) was investigated in laboratory-grade water (LGW) and a local surface water using a low-pressure ultraviolet batch reactor. The PhACs selected in this study belong to different therapeutic classes and are known to occur in environmental samples. Fundamental photolysis and advanced oxidation process parameters obtained in LGW (such as the decadic molar absorption coefficient, quantum yield, and degradation rate constants) are reported and discussed. These parameters, together with the incident photon irradiance, solution depth, and solution absorbance were used to develop UV and UV/ H202 photolysis models that were compared with experimental results obtained in the surface water. The model predicted the experimental UV photolysis removals well but underestimated the UV/H2O2 photolysis results. These models were used to discuss the effects of optical path length and H2O2 concentration on the UV-based rate constant predictions.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555805 · Cited by 12,332
Heberer, T. (2002) · Toxicology Letters · doi:10.1016/s0378-4274(02)00041-3 · Cited by 2,995
Oxidation of Pharmaceuticals during Ozonation and Advanced Oxidation Processes
Huber, M. M., Canonica, S., Park, G.-Y., & von Gunten, U. (2003) · Environmental Science & Technology · doi:10.1021/es025896h · Cited by 1,615
Environmental organic chemistry
(1993) · Choice Reviews Online · doi:10.5860/choice.30-6184 · Cited by 1,325
H2O2 Determination by the I3- Method and by KMnO4 Titration
Klassen, N. V., Marchington, D., & McGowan, H. C. E. (1994) · Analytical Chemistry · doi:10.1021/ac00090a020 · Cited by 955
Rosenfeldt, E. J., & Linden, K. G. (2004) · Environmental Science & Technology · doi:10.1021/es035413p · Cited by 581
Self-citationPacker, J. L., Werner, J. J., Latch, D. E., McNeill, K., & Arnold, W. A. (2003) · Aquatic Sciences - Research Across Boundaries · doi:10.1007/s00027-003-0671-8 · Cited by 446
Kinetic and chemical assessment of the UV/H2O2 treatment of antiepileptic drug carbamazepine
Vogna, D., Marotta, R., Andreozzi, R., Napolitano, A., & d’Ischia, M. (2004) · Chemosphere · doi:10.1016/s0045-6535(03)00757-4 · Cited by 364
Sharpless, C. M., & Linden, K. G. (2003) · Environmental Science & Technology · doi:10.1021/es025814p · Cited by 275
Self-citationReactivity of the carbonate radical with aniline derivatives
Larson, R. A., & Zepp, R. G. (1988) · Environmental Toxicology and Chemistry · doi:10.1002/etc.5620070403 · Cited by 195
Cited by
Patel, M., Kumar, R., Kishor, K., Mlsna, T., Pittman, C. U., & Mohan, D. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00299 · Cited by 2,654
Multiple Roles of Dissolved Organic Matter in Advanced Oxidation Processes
Yang, X., Rosario-Ortiz, F. L., Lei, Y., Pan, Y., Lei, X., & Westerhoff, P. (2022) · Environmental Science & Technology · doi:10.1021/acs.est.2c01017 · Cited by 459
Degradation of selected pharmaceuticals in aqueous solution with UV and UV/H2O2
Yuan, F., Hu, C., Hu, X., Qu, J., & Yang, M. (2009) · Water Research · doi:10.1016/j.watres.2009.01.008 · Cited by 364
Photodegradation and toxicity changes of antibiotics in UV and UV/H2O2 process
Yuan, F., Hu, C., Hu, X., Wei, D., Chen, Y., & Qu, J. (2011) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2010.10.040 · Cited by 317
Pereira, V. J., Linden, K. G., & Weinberg, H. S. (2007) · Water Research · doi:10.1016/j.watres.2007.05.056 · Cited by 272
Self-citationPhotodegradation of pharmaceuticals and personal care products during UV and UV/H2O2 treatments
Kim, I., Yamashita, N., & Tanaka, H. (2009) · Chemosphere · doi:10.1016/j.chemosphere.2009.07.041 · Cited by 266
Li, W., Jain, T., Ishida, K., & Liu, H. (2017) · Environmental Science: Water Research & Technology · doi:10.1039/c6ew00242k · Cited by 151
Kinetics and mechanisms of pH-dependent degradation of halonitromethanes by UV photolysis
Fang, J.-Y., Ling, L., & Shang, C. (2013) · Water Research · doi:10.1016/j.watres.2012.11.050 · Cited by 88
Metadata
- Authors
- Pereira, V. J., Weinberg, H. S., Linden, K. G., & Singer, P. C.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-01-23
- Volume
- 41
- Issue
- 5
- Pages
- 1682-1688
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2038640480
- Cited by
- 332
- References
- 12
- FWCI
- 10.39
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
